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Chemistry of Heterocyclic Compounds

, Volume 4, Issue 6, pp 700–701 | Cite as

Studies on quinones

X. Addition to phenanthrene quinone furazan
  • M. V. Gorelik
  • L. S. Shibryaeva
Article
  • 30 Downloads

Abstract

Phenanthro[1, 2-c][1, 2, 5]oxadiazole-10, 11-dione (phenanthrene quinone furazan, I), like anthraquinone furazan, is capable of adding nucleophilic agents to carbon atom 4 of the carbon skeleton or to the oxygen of the carbonyl group. Thus, its reactions with thiophenol and benzenesulfinic acid, with subsequent oxidation lead, respectively, to the substituted quinones II and IV, the latter of which is converted by the action of benzenesulfinic acid into the benzenesulfonic ester V.

Keywords

Oxidation Oxygen Ester Carbonyl Carbon Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

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    M. V. Gorelik, S. B. Lantsman, and T. P. Kononova, KhGS [Chemistry of Heterocyclic Compounds], 4, 808, 1968.Google Scholar
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    M. V. Gorelik, KhGS [Chemistry of Heterocyclic Compounds], 3, 541, 1967.Google Scholar
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    M. V. Gorelik and S. B. Lantsman, KhGS [Chemistry of Heterocyclic Compounds], 4, 453, 1968,Google Scholar
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    M. V. Gorelik, B. E. Zaitsev, T. P. Kononova, and N. S. Dokunikhin, KhGS [Chemistry of Heterocyclic Compounds], 4, 780, 1968.Google Scholar
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    S. V. Bogdanov and L. S. Shibryaeva, ZhOKh, 33, 1978, 1963.Google Scholar

Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • M. V. Gorelik
    • 1
  • L. S. Shibryaeva
    • 1
  1. 1.Scientific-Research Institute for Organic Intermediates and DyesMoscow

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