Skip to main content
SpringerLink
Log in

Synthesis and properties of heterocyclic analogs of 4-azidochalcone

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A study has been made of the spectral and photochemical properties of a series of heterocyclic analogs of 4-azidochalcone, specifically the pyridine, quinoline, isoquinoline, and quinoxaline derivatives. It has been shown that the absorption spectra of most of the 4-azidocinnamoylarenes are shifted bathochromically in comparison with 4-azidochalcone. The quantum yields of photodissociation of the compounds that were investigated were found to vary within the limits 0.70±0.15. With steric hindrance for the planar conformation of the molecule, a hypsochromic shift of the absorption spectra is observed, along with a slight decrease of the quantum yield.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature Cited

  1. Prospects and Possibilities in Nonsilver Photography [in Russian], Khimiya, Leningrad (1988), p. 90.

  2. A. V. El'tsov (ed.), Light-Sensitive Polymeric Materials [in Russian], Khimiya, Leningrad (1985).

    Google Scholar 

  3. T. A. Zueva, V. M. Treushnikov, and A. V. Oleinik, Zh. Nauchn. Prikl. Fotogr. Kinematogr., 30, 44 (1985).

    Google Scholar 

  4. S. A. Tsukerman, Ch. K. Shon, and V. F. Lavrushin, Zh. Obshch. Khim., 34, 2881 (1964).

    Google Scholar 

  5. L. J. Bellamy, The Infra-Red Spectra of Complex Molecules, 2nd edn., Methuen, London (1958).

    Google Scholar 

  6. M. F. Budyka, M. M. Kantor, and A. P. Pleshkova, Khim. Geterotsikl. Soedin., No. 5, 660 (1991).

    Google Scholar 

  7. B. R. Brown, J. Am. Chem. Soc., 71, 2577 (1949).

    Google Scholar 

  8. A. Kaufmann, H. Peyer, and V. Kunkler, Ber. Dtsch. Chem. Ges., 45, 3093 (1912).

    Google Scholar 

  9. T. C. Bruice, J. Am. Chem. Soc., 79, 702 (1957).

    Google Scholar 

  10. G. S. Kolesnikov, Synthesis of Vinyl Derivatives of Aromatic and Heterocyclic Compounds [in Russian], Moscow (1960), p. 251.

  11. Sint. Geterotsikl. Soedin., No. 7, 17 (1966).

  12. G. Henscke and K. J. Bahner, Chem. Ber., 91, 1605 (1958).

    Google Scholar 

  13. J. J. Padbury and H. G. Lindwall, J. Am. Chem. Soc., 67, 1268 (1945).

    Google Scholar 

  14. F. Sachs and H. Barschall, Ber. Dtsch. Chem. Ges., 34, 3047 (1901).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Chernogolovka Branch, Russian Academy of Sciences, USSR

    M. F. Budyka, M. M. Kantor & M. V. Alfimov

Authors
  1. M. F. Budyka
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Kantor
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Alfimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1340–1343, October, 1991.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Budyka, M.F., Kantor, M.M. & Alfimov, M.V. Synthesis and properties of heterocyclic analogs of 4-azidochalcone. Chem Heterocycl Compd 27, 1072–1075 (1991). https://doi.org/10.1007/BF00486800

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00486800

Keywords

Search

Navigation