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Synthesis and study of the spectral properties of diquinone derivatives of hematoporphyrin IX

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Diquinone derivatives of hematoporphyrin IX with different structures of the quinone fragments were synthesized by the method of mixed anhydrides. The compounds obtained were investigated by UV, IR, PMR, and fluorescence spectroscopy. Pronounced quenching of the fluorescence of porphyrin in the porphyrin quinones, which depends on the acceptor properties of the quinones and the spatial orientation of the donor and acceptor, was observed.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 117571, Moscow

    V. V. Borovkov, A. A. Gribkov, R. P. Evstigneeva, I. A. Struganova, G. V. Ponomarev, G. V. Kirillova, B. V. Rozynov, P. V. Bondarenko, R. A. Zuborev & A. N. Knysh

  2. Institute of Biophysics, Russian Ministry of Public Health, 123182, Moscow

    V. V. Borovkov, A. A. Gribkov, R. P. Evstigneeva, I. A. Struganova, G. V. Ponomarev, G. V. Kirillova, B. V. Rozynov, P. V. Bondarenko, R. A. Zuborev & A. N. Knysh

Authors
  1. V. V. Borovkov
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  2. A. A. Gribkov
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  3. R. P. Evstigneeva
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  4. I. A. Struganova
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  5. G. V. Ponomarev
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  6. G. V. Kirillova
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  7. B. V. Rozynov
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  8. P. V. Bondarenko
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  9. R. A. Zuborev
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  10. A. N. Knysh
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1324–1330, October, 1991,

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Borovkov, V.V., Gribkov, A.A., Evstigneeva, R.P. et al. Synthesis and study of the spectral properties of diquinone derivatives of hematoporphyrin IX. Chem Heterocycl Compd 27, 1059–1064 (1991). https://doi.org/10.1007/BF00486797

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  • DOI: https://doi.org/10.1007/BF00486797

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