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The synthesis and characterization of the molecular sieve SAPO-16 as well as other SAPO and CoAPO phases using bis(cyclopentadienyl) cobalt(III) hydroxide as a structure directing agent

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Abstract

The clathrate type molecular sieve SAPO-16 was prepared via a hydrothermal synthesis using bis(cyclopentadienyl)cobalt(III) hydroxide, Cp2CoOH, as a template and characterized by XRD, FT-IR, UV-Vis and SEM. Additionally, the preparation and characterization of possibly new isostructural SAPO-UTD-3 and CoAPO-UTD-3 materials is reported.

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Authors and Affiliations

  1. Department of Chemistry, University of Texas at Dallas, 75083-0688, Richardson, TX, USA

    Kenneth J. Balkus Jr., Alexei G. Gabrielov & Netanya Sandler

Authors
  1. Kenneth J. Balkus Jr.
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  2. Alexei G. Gabrielov
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  3. Netanya Sandler
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NSF Presidential Young Investigator 1991–1996.

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Balkus, K.J., Gabrielov, A.G. & Sandler, N. The synthesis and characterization of the molecular sieve SAPO-16 as well as other SAPO and CoAPO phases using bis(cyclopentadienyl) cobalt(III) hydroxide as a structure directing agent. J Porous Mater 1, 199–206 (1995). https://doi.org/10.1007/BF00486658

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  • DOI: https://doi.org/10.1007/BF00486658

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