Abstract
New hybrid organic-inorganic gels have been obtained by reaction of 1,4-butanediol, on tetramethoxysilane Si(OMe)4 dissolved in CCl4. This reaction does not require water and leads to the formation of polymeric transparent materials.
Infrared, 29Si and 13C NMR spectroscopy shows that interchange reactions between OMe groups of alkoxide and -O-(CH2)4-O of 1,4-butanediol occurred, leading to the monolithic transparent gels in which both organic (Si-O-(CH2)4-O-Si) and inorganic (Si-O-Si) bridges are formed.
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Amara, C.B., Gharbi, N. & Zarrouk, H. Elaboration and characterization of hybrid organic-inorganic gels obtained by reaction of 1,4-butanediol on tetramethoxysilane. J Sol-Gel Sci Technol 2, 193–197 (1994). https://doi.org/10.1007/BF00486240
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DOI: https://doi.org/10.1007/BF00486240