Abstract
Hydrolytic polycondensation of vinyltrimethoxysilane (VTM) was investigated in detail to prepare vinylpolysiloxanes (VPS) having spinnability and tough gel films. VTM was hydrolyzed in various molar ratios r1 (H2O/VTM) = 0.5–1.6 (HCl/VTM = 0.105, EtOH/VTM = 1.44) at 70°C under a N2 stream with stirring at 150 rpm to give vinylpolysiloxanes with \(\overline {{\text{Mn}}} \)=510–2100 (\(\overline {{\text{Mw}}} /\overline {{\text{Mn}}} \)=1.1–10.4). The controlled hydrolysis in r1 = 1.40–1.64 formed VPSs having the various degrees of spinnability at N2 flow rates of 100–500 ml/min. Transparent films of thickness 0.1–0.05 mm and tensile strength 5–16 MPa were prepared when a 20 wt% acetonemethanol (1:1, V/V) solution of VPS (r1=1.64) was cast at 80°C for several ten days. The reaction was followed by 29Si-NMR spectroscopy to investigate the distribution of unit structures T1, T2 and T3 in VPS depending on r1.
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Abe, Y., Namiki, T., Tuchida, K., Nagao, Y., and Misono, T., J. Non-Cryst. Solids, 147–148 (1991) 47, and the references cited in.
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Abe, Y., Taguchi, K., Hatano, H. et al. Hydrolytic polycondensation of vinyltrimethoxysilane and formation of vinylpolysiloxane films. J Sol-Gel Sci Technol 2, 131–134 (1994). https://doi.org/10.1007/BF00486226
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DOI: https://doi.org/10.1007/BF00486226