Fresenius' Zeitschrift für analytische Chemie

, Volume 335, Issue 1, pp 58–62 | Cite as

Improvement of the analytical possibilities of dual-column ion-chromatography

  • O. A. Shpigun
  • Y. A. Zolotov
Original Papers Chromatographic Methods


Dual-column ion-chromatography is an effective method for determining organic and inorganic ions, especially anions, in different natural and industrial objects. In a number of cases, however, some problems occur limiting its analytical possibilities. These problems are connected with the limited choice of eluents and sorbents, with insufficient selectivity for some objects, unsatisfactory rapidity of determination, and with the occurrence of water dips and system peaks in the chromatogram. In order to solve these problems and improve the analytical possibilities of dualcolumn ion-chromatography it is suggested to use aminoacid eluents, stepwise elution and complex formation of the ions being determined and eluted.


Physical Chemistry Analytical Chemistry Inorganic Chemistry Complex Formation Limited Choice 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Verbesserung der analytischen Möglichkeiten der Doppelsäulen-Ionen-Chromatographie


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Small H, Stevens TS, Bauman WC (1975) Anal Chem 47:1801–1809Google Scholar
  2. 2.
    Smith FC, Chang RC (1983) The practice of ion chromatography. Wiley, New YorkGoogle Scholar
  3. 3.
    Weiss J (1985) Handbuch der Ionenchromatographie. VCH Verlagsgesellschaft, WeinheimGoogle Scholar
  4. 4.
    Gjerde DT, Fritz JS (1987) Ion chromatography. Hüthig, HeidelbergGoogle Scholar
  5. 5.
    Stevens TS, Davis JS, Small H (1981) Anal Chem 53:1488–1492Google Scholar
  6. 6.
    Ishibashi W, Kikuchi R, Yamamoto K (1982) Bunseki Kagaku 31:207–211Google Scholar
  7. 7.
    Haldna U, Palvadre R, Pentshuk J, Kleemeier T (1985) J Chromatogr 350:296–298Google Scholar
  8. 8.
    Dolgonosov AM (1984) Zh Phys Khim 48:1989–1991Google Scholar
  9. 9.
    Shpigun OA, Obrezkov ON, Rubinshtein RN (1986) Uch Zap Tartusskogo Univ 743:185–191Google Scholar
  10. 10.
    Shpigun OA, Obrezkov ON, Voloshik JN, Zolotov JA (1985) Zh Anal Khim 40:1925–1929Google Scholar
  11. 11.
    Shpigun OA, Voloshik JN, Zolotov JA (1985) Anal Sci 1:335–339Google Scholar
  12. 12.
    Shpigun OA, Voloshik JN, Zolotov JA (1987) Zh Anal Khim 42:1209–1215Google Scholar
  13. 13.
    Zolotov JA, Pazukhina JE, Shpigun OA, Voloshik JN, Litvina ML (1987) Dokl Akad Nauk SSR 297:105–107Google Scholar
  14. 14.
    Pazukhina JE, Shpigun OA, Voloshik JN, Litvina ML (1988) Zh Anal Khim 43:117–119Google Scholar
  15. 15.
    Obrezkov ON (1988) PhD thesis, Moscow State University, Moscow D2.00.D2, USSRGoogle Scholar
  16. 16.
    Zolotov JA, Shpigun DA, Pazukhina JE, Voloshik JN (1987) Int J Environ Anal Chem 31:99–105Google Scholar
  17. 17.
    Shpigun OA, Voloshik JN, Zolotov JA (1987) Zh Anal Khim 42:998–1005Google Scholar
  18. 18.
    Ivanov AA, Shpigun OA, Zolotov JA (1986) Zh Anal Khim 41:134–139Google Scholar
  19. 19.
    Ivanov AA, Shpigun OA, Zolotov JA (1987) Zh Anal Khim 42:694–698Google Scholar
  20. 20.
    Purdin SV, Krivolapov SS, Shpigun OA (1987) Zavod Lab 53:12–13Google Scholar

Copyright information

© Springer-Verlag 1989

Authors and Affiliations

  • O. A. Shpigun
    • 1
  • Y. A. Zolotov
    • 1
  1. 1.Chemistry DepartmentLomonosov Moscow State UniversityMoscow V-234USSR

Personalised recommendations