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Spectrophotometric investigation of complexes with organic reagents for the optimization of spectrophotometric determinations (uv + vis) of inorganic analytes

Spektralphotometrische Untersuchung von Komplexverbindungen mit organischen Reagentien für die Optimierung spektralphotometrischer Bestimmungen (uv + vis) eines anorganischen Analyts

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Zusammenfassung

Die Kenntnis von Komplexbildungsgleichgewichten der Elemente mit organischen Reagentien in Lösung, der thermodynamischen und optischen Parameter der Komplexe und deren Verteilung im System ist für die Auswahl optimaler Bedingungen für eine spektralphotometrische Elementbestimmung (uv + vis) wichtig. Alle notwendigen Parameter sind auf Grund einer eingehenden graphischen und mathematischen Interpretation spektralphotometrischer Daten zugänglich. Dieser Weg wird als Beispiel an drei ausgewählten spektralphotometrischen Reagentien, 4-(2-Pyridylazo)resorcin, 2-(2-Thiazolylazo)-4-methoxyphenol und 2-(2-Pyridylazo)-1-naphthol-4-sulfonsäure, gezeigt.

Summary

The knowledge of complex equilibria of elements with organic analytical reagents in solutions and that of thermodynamic and optical parameters of complexes and their distribution in the system is of considerable importance for the selection of optimal conditions for an exact spectrophotometric determination (uv + vis) of an element. All necessary parameters are available by means of a detailed graphical and numerical interpretation of spectrophotometric data. This approach is shown by example of some chromogenic reactions of 4-(2-pyridylazo)resorcin, 2-(2-thiazolylazo)-4-methoxyphenol and 2-(2-pyridylazo)-1-naphthol-4-sulphonic acid.

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References

  1. Umland, F.: Theorie und praktische Anwendung von Komplexbildnern. Frankfurt am Main: Akad. Verlagsges. 1971

    Google Scholar 

  2. Holzbecher, Z. et al.: Handbook of organic reagents in inorganic analysis, p. 183. Chichester: E. Horwood, Ltd. 1976

    Google Scholar 

  3. Sandell, E. B., Onishi, H.: Photometric determination of traces of metals (general aspects), Part I, 4th Edit. New York: J. Wiley and Sons 1978

    Google Scholar 

  4. Zolotov, Yu. A.: Analyst 103, 56 (1978)

    Google Scholar 

  5. Veening, H., Willeford, B. R.: Rev. Inorg. Chem., 1, No. 3, 281 (1979)

    Google Scholar 

  6. Häring, N., Ballschmiter, K.: Talanta 22, 873 (1980)

    Google Scholar 

  7. Schwedt, G.: Chromatographia 12, 613 (1979)

    Google Scholar 

  8. König, K. H., Ehmcke, H. V., Schneeweis, G., Steinbuch, B.: Fresenius Z. Anal. Chem. 297, 411 (1979)

    Google Scholar 

  9. Gaetani, E., Laurezi, C. F., Mangia, A.: Ann. Chim. (Roma) 69, 181 (1979)

    Google Scholar 

  10. Drugov, Yu. S.: Zh. Anal. Khim. 35, 559 (1980)

    Google Scholar 

  11. Hering, R.: Chelatbildende Ionenaustauscher. Berlin: Akad. Verlag 1967

    Google Scholar 

  12. Blasius, E. et al.: Fresenius Z. Anal. Chem. 284, 337 (1977)

    Google Scholar 

  13. Dubský, J. V.: Mikrochem. verein. Mikrochim. Acta 28, 145 (1940)

    Google Scholar 

  14. Feigl, F.: Chemistry of specific, selective and sensitive reactions. New York: Acad. Press 1949

    Google Scholar 

  15. Freiser, H.: Analyst 77, 830 (1952)

    Google Scholar 

  16. Schwarzenbach, G.: Anal. Chem. 32, 6 (1960)

    Google Scholar 

  17. Schwarzenbach, G.: Wiss. Z. Karl-Marx-Univ. Leipzig, Math.Naturwiss. R. 24, H. 4, 349 (1975)

    Google Scholar 

  18. Sommer, L.: Allg. Prakt. Chem. 1967, 29

  19. Martell, A. E., Calvin, M.: Chemistry of the metal chelate compounds. New York: Prentice-Hall 1956

    Google Scholar 

  20. Burger, K.: Organic reagents in metal analysis. Budapest: Akad. Kiado 1973

    Google Scholar 

  21. Beck, M. T.: Chemistry of complex equilibria. Budapest and London: Akad. Kiadó and van Nostrand, Reinhold Co. 1970

    Google Scholar 

  22. Pilipenko, A. T., Savranskii, L. I.: Zh. Anal. Khim. 32, 422 (1977)

    Google Scholar 

  23. Pearson, R. G.: J. Am. Chem. Soc. 85, 3533 (1963)

    Google Scholar 

  24. Röder, H.: Thesis, Bergakad. Freiberg/Sachsen 1979

    Google Scholar 

  25. Ackermann, G., Röder, H.: Talanta 24, 99 (1977)

    Google Scholar 

  26. Savvin, S. B., Kuzin, E. L.: Elektronnye spektry i struktura org. reagentov. Moskva: Nauka 1974, p. 277

    Google Scholar 

  27. Savvin, S. B., Gribov, L. A., Lebedev, V. L., Likhonina, E. A.: Zh. Anal. Khim. 26, 2108 (1971)

    Google Scholar 

  28. Pilipenko, A. T., Savranskii, L. I.: Talanta 25, 451 (1978)

    Google Scholar 

  29. Pilipenko, A. T., Savranskii, L. I., Skorokhod, E. G.: Zh. Anal. Khim. 27, 1080 (1972)

    Google Scholar 

  30. Savvin, S. B., Kuzin, E. L.: Zh. Anal. Khim. 22, 1058 (1967)

    Google Scholar 

  31. Kuzin, E. L., Likhonina, E. A., Savvin, S. B.: Zh. Anal. Khim. 27, 350 (1972)

    Google Scholar 

  32. Savvin, S. B.: Zh. Anal. Khim. 28, 130 (1973)

    Google Scholar 

  33. Gribov, L. A., Savvin, S. B., Raikhshtat, M. M.: Zh. Anal. Khim. 31, 1504 (1976)

    Google Scholar 

  34. Savvin, S. B., Raikhshtat, M. M., Gribov, L. A.: Zh. Anal. Khim. 31, 1869 (1976)

    Google Scholar 

  35. Kankare, J. J.: Anal. Chem. 42, 1322 (1972)

    Google Scholar 

  36. Sommer, L., Kučerová, J., Procházková, H., Hniličková, M.: Publ. Fac. Sci. Nat. Univ. Brno, No. 464, 249 (1965)

    Google Scholar 

  37. Havel, J., Sommer, L., Collect. Czechoslov. Chem. Commun. 34, 2674 (1969)

    Google Scholar 

  38. Sommer, L., Kubáň, V., Havel, J.: Folia Fac. Sci. Nat. Univ. Brum. 11, Chem. 7, Part 1 (1970)

  39. Voznica, P., Havel, J., Sommer, L.: Collect. Czechoslov. Chem. Commun. 45, 54 (1980)

    Google Scholar 

  40. Havel, J., Kubáň, V.: Scripta Fac. Sci. Nat. Univ. Brun., Chemia 2, (1), 87 (1971)

    Google Scholar 

  41. Kubáň, V.: Scripta Fac. Sci. Nat. Univ. Brun. Chemia 2, (2), 81 (1972)

    Google Scholar 

  42. Koch, S., Weber, P., Ackermann, G.: Chem. Anal. (Warsaw) 23, 563 (1978)

    Google Scholar 

  43. Ostromysslensky, I.: Ber. Deut. Chem. Ges. 34, 268 (1911)

    Google Scholar 

  44. Job, P.: Ann. Chim. (Paris) 10, (9), 113 (1928); 11, (6), 97 (1936)

    Google Scholar 

  45. Sommer, L., Hniličková, M.: Bull. Soc. Chim. France 1959, 36

  46. Havel, J., Rabová, D., Sommer, L.: Scripta Fac. Sci. Nat. Univ. Brun. Chemia 3, (7), 101 (1977)

    Google Scholar 

  47. Likussar, W., Boltz, D. F.: Anal. Chem. 45, 1265 (1973)

    Google Scholar 

  48. Likussar, W.: Anal. Chem. 46, 1296 (1974)

    Google Scholar 

  49. Havel, J., Pavlíková, N.: not yet published.

  50. Sillén, L. G., Warnquist, B.: Acta Chem. Scand. 22, 3032 (1968); Ark. Kemi 31, 377 (1969)

    Google Scholar 

  51. Havel, J.: Trans. Royal Inst. Techn. Stockholm, Nr. 277 (1972)

  52. Suchánek, M., Šůcha, L.: Sborník VŠCHT, Praha H 13, 41 (1978)

  53. Legget, D. J., Bryde, W. A. E.: Anal. Chem. 47, 1065 (1975)

    Google Scholar 

  54. Leggett, D. J.: J. Chem. Educat. 51, 502 (1974)

    Google Scholar 

  55. Jančář, L., Havel, J., Kubáň, V., Sommer, L.: Collect. Czechoslov. Chem. Commun., in press

  56. Ingri, N., Kakolowitz, W., Sillén, L. G., Warnqwist, B.: Talanta 14, 1251 (1967)

    Google Scholar 

  57. Havel, J., Kubáň, V.: Scripta Fac. Sci. Nat. Univ. Brun., Chemia 2, 2, 95 (1972)

    Google Scholar 

  58. Havel, J.: Scripta Fac. Sci. Nat. Univ. Brun., Chemia 4, 3, 117 (1973)

    Google Scholar 

  59. Havel, J., Pavlíková, N., Horák, J.: Scripta Fac. Sci. Nat. UJEP Brno, in press

  60. Kubáň, V.: Chem. Listy 74, 862 (1980)

    Google Scholar 

  61. Havel, J.: Chem. Listy 62, 1250 (1968)

    Google Scholar 

  62. Kubáň, V., Havel, J., Sommer, L.: Collect. Czechoslov. Chem. Commun. 40, 604 (1975)

    Google Scholar 

  63. Liteanu, C., Riča, J.: Pure Appl. Chem. 44, 535 (1975)

    Google Scholar 

  64. ACS Committee on Environmental Improvement; Anal. Chem. 52, 2242 (1980)

    Google Scholar 

  65. Sommer, L., Langová, M., Kubáň, V.: Scripta Fac. Sci. Nat. Univ. Brun., Chemia 1, 8, 13 (1978)

    Google Scholar 

  66. Ackermann, G., Köthe, J., Koch, S.: Scripta Fac. Sci. Nat. Univ. Brun., Chemia 1, 8, 1 (1978)

    Google Scholar 

  67. Sommer, L., Langová, M., Kubáň, V., Ackermann, G., Köthe, J., Koch, S.: Scripta Fac. Sci. Nat. Univ. Brun., No. 1–2 (Chemia) 10, 71 (1980)

    Google Scholar 

  68. Langová, M., Sommer, L.: Folia Fac. Sci. Nat. Univ. Brun. 9, Chemia 2, Part 2 (1968)

  69. Ivanov, V. M.: Zh. Anal. Khim. 31, 993 (1976); Usp. Khim. 45, 456 (1976)

    Google Scholar 

  70. Shibata, S.: in: Chelates in anal. chemistry; H. A. Flaschka and A. J. Barnard, Eds., Vol. 4, p. 1. New York: M. Decker 1972

    Google Scholar 

  71. Sommer, L.: Wiss. Z. Karl-Marx-Univ., Leipzig, Math.-Naturwiss. R. 24, H. 4, 417 (1975)

    Google Scholar 

  72. Voštová, J., Sommer, L.: Collect. Czechoslov. Chem. Commun. 41, 1137 (1976)

    Google Scholar 

  73. Hrdlička, A., Langová, M.: Collect. Czechoslov. Chem. Commun. 45, 1502 (1980)

    Google Scholar 

  74. Tataev, O. A., Akhmedov, S. A., Akhmedova, Ch. A.: Zh. Anal. Khim. 24, 834 (1969)

    Google Scholar 

  75. Kowalska, Z.: Chem. Anal. (Warsaw) 16, 197 (1969)

    Google Scholar 

  76. Nonova, D., Evtimova, B.: Anal. Chim. Acta 62, 456 (1972)

    Google Scholar 

  77. Corsini, A., Mai-Ling Yih, I., Fernando, Q., Freiser, H.: Anal. Chem. 34, 1090 (1962)

    Google Scholar 

  78. Corsini, A., Fernando, Q., Freiser, H.: Inorg. Chem. 2, 224 (1963)

    Google Scholar 

  79. Evtimova, B., Nonova, D.: Anal. Chim. Acta 49, 103 (1970)

    Google Scholar 

  80. Šimek, Z., Langová, M., Sommer, L.: Collect. Czechoslov. Chem. Commun., in press

  81. Shijó, Y., Takeuchi, T.: Bunseki Kagaku 14, 511 (1965)

    Google Scholar 

  82. Nevoral, V., Okáč, A.: Čs. Farm. 17, 478 (1968)

    Google Scholar 

  83. Kristiansen, H., Langmyhr, F. J.: Acta Chem. Scand. 13, 1473 (1959)

    Google Scholar 

  84. Dagnall, R. M., West, T. S., Young, P.: Talanta 12, 583 (1965)

    Google Scholar 

  85. Geary, W. J., Nickless, G., Pollard, F. H.: Anal. Chim. Acta 27, 71 (1962)

    Google Scholar 

  86. Pollard, F. H., Hanson, P., Geary, W.: Anal. Chim. Acta 20, 26 (1959)

    Google Scholar 

  87. Klečková, Z., Langová, M., Havel, J.: Collect. Czechoslov. Chem. Commun. 43, 3163 (1978)

    Google Scholar 

  88. Pollak, M., Kubáň, V.: Collect. Czechoslov. Chem. Commun. 44, 725 (1979)

    Google Scholar 

  89. Tanaka, M., Funahashi, S., Shirai, K.: Anal. Chim. Acta 39, 437 (1967); Inorg. Chem. 7, 573 (1968)

    Google Scholar 

  90. Nonova, D., Nenov, V., Lihareva, N.: Talanta 23, 679 (1976)

    Google Scholar 

  91. Hniličková, M., Sommer, L.: Collect. Czechoslov. Chem. Commun. 26, 2189 (1961)

    Google Scholar 

  92. Geary, W. J., Nickless, G., Pollard, F. H.: Anal. Chim. Acta 26, 575 (1962)

    Google Scholar 

  93. Iwamoto, T.: Bull. Chem. Soc. Japan 34, 605 (1961)

    Google Scholar 

  94. Kitano, M., Ueda, J.: Nippon Kagaku Zasshi 91, 983 (1970); Anal. Abstr. 22, 52 (1972)

    Google Scholar 

  95. Ahrland, S., Herman, R. G.: Anal. Chem. 47, 2422 (1975)

    Google Scholar 

  96. Vlčková, S., Jančář, L., Kubáň, V., Havel, J.: Collect. Czechoslov. Chem. Commun., in press

  97. Kitano, M., Ueda, L.: Nippon Kagaku Zasshi 91, 760 (1970); Anal. Abstr. 21, 4011 (1971)

    Google Scholar 

  98. Chromý, V., Sommer, L.: Talanta 14, 393 (1967)

    Google Scholar 

  99. Langová, M., Machálková, D., Sommer, L.: Scripta Fac. Sci. Nat. Univ. Brun., Chemia 2, 2, 229 (1972)

    Google Scholar 

  100. Hovind, H. R.: Analyst 100, 769 (1975)

    Google Scholar 

  101. Kubáň, V., Havel, J.: Acta Chem. Scand. 27, 528 (1973)

    Google Scholar 

  102. Langová, M., Havel, J., Sommer, L.: Chem. Anal. (Warsaw) 17, 989 (1972)

    Google Scholar 

  103. Kai, F.: Anal. Chim. Acta 44, 242 (1969)

    Google Scholar 

  104. Kubáň, V., Sommer, L.: Scripta Fac. Sci. Nat. Univ. Brun. Chemia 1, 6, 17 (1976)

    Google Scholar 

  105. ZbíralJ., Sommer, L.: Scripta Fac. Sci. Nat. Univ. Brun., in press

  106. Chromý, V., Sommer, L.: Publ. Fac. Sci. Univ. Brno No. 517, 407 (1970)

    Google Scholar 

  107. Kubáň, V., Sommer, L.: Collect. Czechoslov. Chem. Commun. 40, 2032 (1975)

    Google Scholar 

  108. Anderson, R. C., Nickless, G.: Analyst 93, 13 (1968)

    Google Scholar 

  109. Sommer, L., Koblížková-Danešová, V.: Collect. Czechoslov. Chem. Commun. 39, 396 (1974)

    Google Scholar 

  110. Koblížková, V., Kubáň, V., Sommer, L.: Collect. Czechoslov. Chem. Commun. 43, 2711 (1978)

    Google Scholar 

  111. Koblížková, V., Kubáň, V., Sommer, L.: Chem. Zvesti 33, 485 (1979).

    Google Scholar 

  112. Ooi, S., Carter, D., Fernando, Q.: Chem. Commun. 1967, 1301

  113. Nonova, D., Pavlova, S.: Anal. Chim. Acta 123, 289 (1981)

    Google Scholar 

  114. Timerbaev, A. R., Petrukhin, O. M., Zolotov, Yu. A.: Zh. Anal. Khim. 36, 1160 (1981)

    Google Scholar 

  115. Janák, K., Janák, J.: Chem. Listy 75, 465 (1981)

    Google Scholar 

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  1. Dept. of Analyt. Chem., J. E. Purkyně-Univ., 61137, Brno, Czechoslovakia

    L. Sommer, V. Kubáň & M. Langová

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  1. L. Sommer
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Dedicated to Prof. Dr. Fritz Umland on the occasion of his 60th birthday

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Sommer, L., Kubáň, V. & Langová, M. Spectrophotometric investigation of complexes with organic reagents for the optimization of spectrophotometric determinations (uv + vis) of inorganic analytes. Z. Anal. Chem. 310, 51–61 (1982). https://doi.org/10.1007/BF00481938

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