Quantitative NRA and SIMS depth profiling of hydrogen in naturally weathered medieval glass

  • M. Schreiner
  • M. Grasserbauer
  • P. March
Inorganic Material

Summary

NRA and SIMS measurements were carried out with samples from naturally weathered medieval glass paintings in order to study the quantitative depth distribution of hydrogen in the surface layers. The major parts of the profiles show good agreements in shape and depth. Nevertheless, differences were observed in the near-surface region. It could be shown that proper attention has to be paid to the vacuum environment of the instruments and to sample preparation before evacuation in order to avoid evaporation of hydrogen containing species incorporated into the silicate structure during leaching or weathering.

Keywords

Hydrogen Evaporation Silicate Inorganic Chemistry Surface Layer 

Quantitative NRA- und SIMS-Tiefenprofilanalyse von Wasserstoff in natürlich verwitterten mittelalterlichen GlÄsern

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Copyright information

© Springer-Verlag 1988

Authors and Affiliations

  • M. Schreiner
    • 1
  • M. Grasserbauer
    • 2
  • P. March
    • 3
  1. 1.Institute of ChemistryAcademy of Fine ArtsViennaAustria
  2. 2.Institute of Analytical ChemistryTechnical UniversityViennaAustria
  3. 3.Institute of Nuclear PhysicsJ.W. Goethe UniversityFrankfurtGermany

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