Chemistry of Heterocyclic Compounds

, Volume 3, Issue 2, pp 510–512 | Cite as

Study of the reaction of sulfur with organic compounds

XIII. Reaction of sulfur with mono-, di-, and tri-exo-halogen-substituted iso- and n-propylbenzenes
  • M. G. Voronkov
  • T. V. Lapina
  • E. P. Popova
Article
  • 44 Downloads

Abstract

A study is made of the action of sulfur on halogen derivatives of iso- and n-propylbenzene, with 1–3 chlorine or bromine atoms at various places in the side chain. Reaction of sulfur with α-chlorocumene, α, β-dichlorocumene, and α, β, β-trichlorocumene and mixtures of these, proves to be a new convenient method of preparing 4-phenyl-1,2-dithio-3-thione (40% yield). Sulfuration of mono-, di- and tri-exo-halogen derivatives of n-propylbenzene gives 5-phenyl-1,2-dithiol-3-thione in 11–18% yield.

Keywords

Halogen Hydrogen Sulfide Heterocyclic Compound Cumene Cinnamyl 

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Copyright information

© The Faraday Press, Inc. 1969

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • T. V. Lapina
    • 1
  • E. P. Popova
    • 1
  1. 1.Institute of Organic SynthesisAS Latvian SSRRiga

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