Abstract
A calculation has been made of the influence of the electric field of π-electronic charges on the chemical shifts of the meso-protons in β-ethoxycarbonyl-substituted porphyrins. A comparison of the calculated and experimental figures shows that the change in the chemical shifts taking place with the introduction of ethoxycarbonyl substituents into the β-position is due mainly to the changes in the π-electronic charges.
References
T. W. Marshall and J. A. Pople, Mol. Phys., 1, 199, 1958.
V. M. Mamaev, G. V. Ponomarev, and R. P. Evstigneeva, KhGS [Chemistry of Heterocyclic Compounds], 3, 861, 1967.
V. M. Mamaev, S. V. Zenin, G. V. Ponomarev, and R. P. Evstigneeva, TEKh (in press).
B. Pullman and A. Pullman, Quantum Biochemistry [Russian translation], Mir, Moscow, 1965.
J. I. Musher, J. Chem. Phys., 37, 34, 1962.
L. Welb and E. Fleisher, J. Am. Chem. Soc., 87, 667, 1965.
P. L. Goodfriend, F. W. Birss, and A. B. F. Duncan, Rev. Mod. Phys., 32, 307, 1960.
M. D. Newton, F. P. Boer, and W. N. Lipscomb, J. Am. Chem. Soc., 88, 2367, 1966.
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Mamaev, V.M., Zenin, S.V., Ponomarev, G.V. et al. Influence of π-electronic charges on the chemical shifts of the meso-protons in β-ethoxycarbonyl-substituted porphyrins. Chem Heterocycl Compd 4, 685–686 (1971). https://doi.org/10.1007/BF00481060
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DOI: https://doi.org/10.1007/BF00481060