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Research on benz- and naphthazoles

XIII. 1-Benzazolyl-3,5-diphenylformazans

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Heterocyclic analogs of triphenylformazan have been synthesized: 1-(1'-benzylbenzimidazolyl)-3,5-diphenylformazan (I), 1-benzothiazolyl-3,5-diphenylformazan (II), and 1-benzoxazolyl-3,5-diphenylformazan (III). On a basis of the study of IR and UV spectra, the hypothesis has been put forward that I lacks a chelate ring while II and III have chelate rings with a weak intramolecular hydrogen bond. Ease of complex formation with many metals and a capacity for the formation of tetrazolium salts have been noted.

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References

  1. N. P. Bednyagina, N. V. Serebryakova, R. I. Ogloblina, and I. I. Mudretsova, KhGS [Chemistry of Heterocyclic Compunds] (in press).

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For part XXII, see [1].

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Bednyagina, N.P., Lipunova, G.N. Research on benz- and naphthazoles. Chem Heterocycl Compd 4, 652–653 (1971). https://doi.org/10.1007/BF00481047

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  • DOI: https://doi.org/10.1007/BF00481047

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