Abstract
By the action of four equivalents of sodium in liquid ammonia on the bis(alkylmercapto)thiophenes I, II, and IX we have obtained the corresponding dimercaptothiophenes VII, IX, and VIII, which were characterizied in the form of their dibenzoyl derivatives XI–XIII. The dimercaptothiophenes VII and VIII and the o-alkylthiothiophenethiols III and IV form the internally complex compounds XIV–XVII with metal acetates.
Similar content being viewed by others
References
S. E. Livingstone, Quart. Revs., 19, 386, 1965.
G. N. Schrauzer and V. P. Mayweg, J. Am. Chem. Soc., 87, 3585, 1965.
R. Williams, E. Billig, J. H. Waters, and H. B. Gray, J. Am. Chem. Soc., 88, 43, 1966.
E. Hoyer and W. Schroth, Chem. a. Ind., 652, 1965.
A. E. Balch, R. H. Holm and F. Röhrscheid, J. Am. Chem. Soc., 87, 2301, 1965.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, OKhN, 701, 1962, 1801, 1963; Izv. AN SSSR, ser. khim., 897, 1966.
W. Schroth and H. Schmidt, Z. Chem., 4, 270, 1964.
S. Gronowitz and P. Moses, Acta Chem. Scand. 16, 105, 1962.
L. J. Pandya and B. D. Tilak, Chem. a. Ind., 918, 1958.
R. Adams and A. Ferretti, J. Am. Chem. Soc., 81, 4939, 1959.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, OKhN, 1696, 1960.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, ZhOKh, 29, 3631, 1959.
Ya. L. Gol'dfarb, M. B. Ibrazimova, and O. A. Kalinovskii, Izv. AN SSSR, OKhN, 1098, 1962.
Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, ZhOKh, 29, 2034, 1959.
Ya. L. Gol'dfarb and M. A. Kalik, KhGS [Chemistry of Heterocyclic Compounds], 3, 1022, 1967.
Author information
Authors and Affiliations
Additional information
For part XIV, see [15].
Rights and permissions
About this article
Cite this article
Gold'dfarb, Y.L., Kalik, M.A. Synthesis and some reactions of sulfides of the thiophene series. Chem Heterocycl Compd 4, 571–573 (1971). https://doi.org/10.1007/BF00481018
Issue Date:
DOI: https://doi.org/10.1007/BF00481018