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Synthesis and some reactions of sulfides of the thiophene series

XV. Synthesis of dimercaptothiophenes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By the action of four equivalents of sodium in liquid ammonia on the bis(alkylmercapto)thiophenes I, II, and IX we have obtained the corresponding dimercaptothiophenes VII, IX, and VIII, which were characterizied in the form of their dibenzoyl derivatives XI–XIII. The dimercaptothiophenes VII and VIII and the o-alkylthiothiophenethiols III and IV form the internally complex compounds XIV–XVII with metal acetates.

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For part XIV, see [15].

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Gold'dfarb, Y.L., Kalik, M.A. Synthesis and some reactions of sulfides of the thiophene series. Chem Heterocycl Compd 4, 571–573 (1971). https://doi.org/10.1007/BF00481018

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