Chemistry of Heterocyclic Compounds

, Volume 2, Issue 2, pp 138–143 | Cite as

Molecular spectra of nitroisoxazolinones

  • A. I. Ivanov
  • V. I. Slovetskii
  • V. A. Tartakovskii
  • S. S. Novikov
Article
  • 25 Downloads

Abstract

A study is made of IR and UV spectra of N-oxides of nitroisoxazolinones, and of derivatives of isoxazolidine and isoxazolizidine. Absorption bands are related to valence vibrations of N-O in the NO2 group; in conjugated systems (in N-oxides of nitroisoxazolines) νs and γas are equal to ∼1310 and ∼1510 cm−1, in nonconjugated systems (in nitroisoxazolidines) ∼1360 and ∼1560 cm−1, respectively. Frequencies of N-O bond vibrations in N-oxides appear in the region 830–870 cm−1, of the O-N-O fragment in isoxazolidines and isoxazolizidines in the 1010–1060 cm−1 region. Measurements are made of total intensities of N-O valence vibrations in the NO2 group in N-oxides of nitroisoxazolines and nitroisoxazolizidines, as well as of C=N valence vibrations in N-oxides of nitroisoxazolines.

Keywords

Organic Chemistry Absorption Band Molecular Spectrum Bond Vibration Valence Vibration 

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Copyright information

© The Faraday Press, Inc. 1967

Authors and Affiliations

  • A. I. Ivanov
    • 1
  • V. I. Slovetskii
    • 1
  • V. A. Tartakovskii
    • 1
  • S. S. Novikov
    • 1
  1. 1.Zelinskii Institute of Organic ChemistryAS USSRMoscow

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