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Use of ESCA for a convenient and semi-quantitative state analysis of copper-nickel alloy surfaces

Einsatz von ESCA für die einfache halbquantitative Zustandsanalyse von Oberflächen von Kupfer-Nickel-Legierungen

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Zusammenfassung

Das ESCA-Verfahren wurde für die Untersuchung des Oberflächenzustandes von KupferNickel-Legierungen eingesetzt. Mit Hilfe der flächenintegrierten Peakintensitäten (L3 M4, 5 M4, 5 für Kupfer, 2 p 3/2 für Nickel) konnten Kupfer(II) und Nickeloxid auf den Legierungen halbquantitativ bestimmt werden. Sauerstoff wurde im interstitiellen (Cu2O, NiO) nichtstöchiometrischen (-OH) und molekularen (adsorbierten) Zustand gefunden. Weiterhin wurde die Oberflächenzusammensetzung der Legierungen nach Erhitzen im Hochvakuum diskutiert.

Summary

A semi-quantitative technique by means of ESCA was applied to the surface state analysis of copper-nickel alloys. With area integrated intensity of peaks at the L3M4, 5M4, 5 region of copper and 2 p 3/2 region of nickel, cuprous state and nickel oxide state on alloys could be semi-quantitatively determined. As to oxygen states on alloy surfaces, interstitial (Cu2O and NiO states), non-stoichiometric (represents -OH) and molecular states (adsorbed) were estimated. Further, the surface composition of alloys after heating under high vacuum was discussed.

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Authors and Affiliations

  1. The Research Institute for Iron, Steel and Other Metals, Tohoku University, Sendai, Japan

    Kichinosuke Hirokawa, Teruo Sato & Masaoki Oku

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  1. Kichinosuke Hirokawa
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  2. Teruo Sato
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  3. Masaoki Oku
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Hirokawa, K., Sato, T. & Oku, M. Use of ESCA for a convenient and semi-quantitative state analysis of copper-nickel alloy surfaces. Z. Anal. Chem. 297, 393–397 (1979). https://doi.org/10.1007/BF00480896

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  • DOI: https://doi.org/10.1007/BF00480896

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