Chemistry of Heterocyclic Compounds

, Volume 27, Issue 4, pp 376–380 | Cite as

Podand-porphyrins with peripheral chelates

  • V. I. Mel'nik
  • Z. I. Zhilina
  • S. A. Andronati
  • V. N. Ganevich
  • M. V. Babchinskaya
Article
  • 41 Downloads

Abstract

Alkylation of 5-(3′-nitro-4′-hydroxyphenyl)-10,15,20-triphenylporphyrin with chloropyridines[2,6-dichloromethyl-and 2-chloromethyl-6-(2′-nitrophenoxymethylpyridine)] as well as condensation by a mixed-aldehyde method starting with formylpyridines [2-(2′-nitro-4′-formylphenoxymethyl)-6-(2′-nitrophenoxy-methyl-) or 2,6-di(2′-nitro-4′-formylphenoxymethyl)pyridine], benzaldehyde, and pyrrole are used to synthesize previously unknown podand-porphyrins containing from one to four peripheral chelates.

Keywords

Organic Chemistry Pyridine Alkylation Pyrrole Benzaldehyde 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. 1.
    S. Sugata and V. Matsusima, Chem. Pharm. Bull., 35, 2623 (1987).Google Scholar
  2. 2.
    K. Marujama, F. Kobayashi, and A. Osuka, Chem. Lett., No. 5, 821 (1987).Google Scholar
  3. 3.
    F. Voegtle and E. Weber (eds.), Host Guest Complex Chemistry: Synthesis, Structures, Applications, Springer-Verlag, Berlin (1985).Google Scholar
  4. 4.
    L. Milgrom, J. Chem. Soc. Perkin Trans. 1, No. 10, 2535 (1983).Google Scholar
  5. 5.
    D. Dolphin, S. Hion, and J. B. Paine, Heterocycles, 16, 417 (1981).Google Scholar
  6. 6.
    A. V. Bogatskii, Z. I. Zhilina, and D. E. Stepanov, Zh. Org. Khim., 18, 2309 (1982).Google Scholar
  7. 7.
    A. V. Bogatskii and Z. I. Zhilina, Usp. Khim., 51, 1034 (1982).Google Scholar
  8. 8.
    Z. I. Zhilina, Yu. V. Ishkov, S. A. Andronati, and I. S. Voloshanovskii, Dokl. Akad. Nauk SSSR, 303, 377 (1988).Google Scholar
  9. 9.
    Z. I. Zhilina, V. I. Mel'nik, S. A. Andronati, and A. E. Abramovich, Zh. Org. Khim., 25, 1063 (1989).Google Scholar
  10. 10.
    Z. I. Zhilina, V. V. Mel'nik, S. A. Andronati, T. N. Dmitrieva, and V. N. Ganevich, Zh. Org. Khim., 25, 1070 (1989).Google Scholar
  11. 11.
    A. S. Semeikin, O. I. Koifman, and B. D. Berezin, Khim. Geterotsikl. Soedin., No. 6, 798 (1986).Google Scholar
  12. 12.
    F. Vögtle, Angew. Chem., 89, 564 (1974).Google Scholar
  13. 13.
    I. Guben, Methods of Organic Chemistry, Vol. 4, No. 1, Book 1 [in Russian], Goskhimizdat, Moscow-Leningrad (1949), p. 277.Google Scholar

Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • V. I. Mel'nik
    • 1
  • Z. I. Zhilina
    • 1
  • S. A. Andronati
    • 1
  • V. N. Ganevich
    • 1
  • M. V. Babchinskaya
    • 1
  1. 1.I. I. Mechnikov Odessa State UniversityOdessa

Personalised recommendations