Abstract
Aliphatic and aromatic hydrocarbons, fatty acids and heavy metals (Pb, Cu, Ni, Zn, Fe and Cd) were analyzed in atmospheric particulate matter in the city of Caracas, Venezuela. Samples were taken from 6 stations within the metropolitan area of Caracas, characterized as industrial (one), urban (two), suburban (two) and rural (one). In addition, the concentration and composition of the organic compounds was monitored over a 5 month period at an urban site to determine seasonal and temporal variabilities.
In general terms, the concentrations of pollutants decreased from industrial and urban sites to suburban to rural. A similar trend was observed for preliminary toxicity tests carried out on the particulate extracts. The concentration levels of most of the pollutants were high for the industrial and urban sites, and comparable with those of other major cities worldwide.
Similar content being viewed by others
References
Alvarado, J., León, L., López, F., and Lima, C.: 1988, J. Atom. Abs. Spec. 3, 135.
Bennett, R., Knapp, K., Jones, P., Wilkerson, J., and Strup, P.: 1979, in Jones, P. W. and Leber, P. (eds.) Polynuclear Aromatic Hydrocarbons, Third International Symposium on Chemistry and Biology — Carcinogenesis and Mutagenesis Ann Arbor Science Publishers Inc., Ann Arbor, pp. 419.
Butler, J., Kneip, T., and Daisey, J.: 1987, Atmos. Environ. 21, 883.
Cabrera, A.: 1990, Tesis de Licenciatura, Universidad Simón Bolívar.
Carrero, H.: 1989, Tesis de Maestría, Universidad Simón Bolívar.
Cautreels, W. and Van Cauwenberghe, K.: 1978, Atmos. Environ. 12, 1133.
Cranwell, P.: 1982, Prog. Lipid Res. 21, 271.
Colmsjö, A., Zebür, Y., and Östman, C.: 1986, Chemosphere 15, 169.
Czuczwa, J., Leuenberger, C., and Giger, W.: 1988, Atmos. Environ. 22, 907.
Davidson, C., Gould, W., Mathison, T., Wiersma, G., Brown, K., and Reilly, M.: 1985, Environ. Sci. Technol. 19, 27.
De Wiest, F.: 1978, Atmos. Environ. 12, 1705.
Doskey, P. and Andren, A.: 1986, Atmos. Environ. 20, 1735.
Eglinton, G. and Hamilton, J. R.: 1967, Science 156, 1322.
Eisenreich, S., Metzer, N., and Urban, N.: 1986, Environ. Sci. Technol. 20, 171.
Escalona, L. and Sanhueza, E.: 1981, Atmos. Environ. 15, 61.
Farmer, C. and Wade, T.: 1986, Water, Air, and Soil Pollut. 29, 439.
Friedlander, S.: 1973, Environ. Sci. Technol. 7, 235.
Halkiewicz, J., Lamparczyk, H., Grzybowski, J., and Radecki, A.: 1987, Atmos. Environ. 21, 2057.
Ishizaki, C. and Sanhueza, E.: 1979, Interciencia 4, 6.
Jaffé, R., Cabrera, A., Carrero, H., and Alvarado, J.: 1993, Water, Air, and Soil Pollut. (This issue).
Kawamura, K. and Kaplan, I.: 1986a, Atmos. Environ. 20, 115.
Kawamura, K. and Kaplan, I.: 1986b, Atmos. Environ. 20, 527.
Kowalczyk, G., Gordom, G., and Rheingrover, S.: 1982, Environ. Sci. Technol. 16, 79.
Laflamme, R. and Hites, R.: 1978, Geochim. et Cosmochim. Acta 42, 289.
Leuenberger, C., Czuczwa, J., Heyerdahl, E., and Giger, W.: 1988, Atmos. Environ. 22, 695.
Lara, V., Bifano, C., and Sanhueza, E.: 1984, Acta Cient. Venez. 35, 369.
Lyall, R., Hooper, M., and Mainwaring, S.: 1988, Atmos. Environ. 22, 2549.
Mackenzie, A.: 1984, Advances in Petroleum Geochemistry, Vol. 1, Academic Press, London.
Maenhaut, W., Zoller, W., Duce, R., and Hoffman, G.: 1979, J. Geophys. Res. 84, 2421.
Manahan, S.: 1979, Environmental Chemistry, Willard Grand Press, Boston, Massachusetts.
Matsumoto, G. and Hanya, T.: 1980, Atmos. Environ. 14, 1409.
Mazurek, M. and Simoneit, B.: 1984, in L. H. Keith (eds), Identification and Analysis of Organic Pollutants in Air, Ann Arbor Science, pp. 353.
Mazurek, M., Cass, G., and Simoneit, B.: 1991, Environ. Sci. Technol. 25, 684.
McVeety, B. and Hites, R.: 1988, Atmos. Environ. 22, 511.
Meyers, P. and Hites, R.: 1982, Atmos. Environ. 16, 2169.
Møller, M., Alfheim, I., Larssen, S., and Mikaisen, A.: 1982, Environ. Sci. Technol. 16, 221.
Morales, J., Escalona, L., Ishizaki, C., and Sanhueza, E.: 1979, J.A.P.C.A. 29, 1072.
Moody, J. and Lindstrom, R.: 1977, Anal. Chem. 49, 2264.
Noller, B., Bloom, H., and Arnold, A.: 1981, Prog. Anal. Atom. Spectrosc. 1, 81.
Nriagu, J.: 1979, Nature 279, 409.
Paciga, J. and Jervis, R.: 1976, Environ. Sci. Technol. 10, 1124.
Peltzer, E., Alford, R., and Gagosian, R.: 1984, Woods Hole Oceanographic Institution, Report WHOI-84-9.
Perry, G. J., Volkman, J. K., Johns, R. B. and Bovor, H. J. Jr.: 1979, Geochim. Cosmochim. Acta 43, 1715.
Ramírez, M. and Vásquez, E.: 1988, MARNR Informe Técnico DGSIIA/II/257.
Rogge, W., Hildemann, L., Mazurek, M., Cass, G., and Simoneit, B.: 1991, Environ. Sci. Technol. 25, 1112.
Ross, H.: 1984, International Meteorological Institute in Stockholm, report CM-67, 35.
Sanhueza, E., Africano, M., and Romero, J.: 1982, The Science of the Total Environment 23, 3.
Sanhueza, E. and Ruiz, M.: 1983, Acta. Cient. Venez. 34, 363.
Sanhueza, E., Serrano, J., and Bifano, C.: 1986, Proceedings of the International Conference of Chemicals in the Environment, Lisboa, Portugal, p. 348.
Schiewe, M., Hawk, E., Actor, D., and Krahn, M.: 1985, Can. J. Fish. Aquat. Sci. 42, 1244.
Sicherer-Roetman, A., Ramlal, M., Voogd, C., and Bloemen, H.: 1988, Atmos. Environ. 22, 2803.
Sicre, M., Marty, J., Saliot, A., Aparicio, X., Grimalt, J., and Albaigés, J.: 1987, Intern. J. Environ. Anal. Chem. 29, 73.
Simoneit, B.: 1977, Mar. Chem. 5, 443.
Simoneit, B.: 1984, Atmos. Environ. 18, 51.
Simoneit, B.: 1985, Int. J. Environ. Anal. Chem. 22, 203.
Simoneit, B. and Mazurek: 1981, CRC Critical Reviews in Environmental Control 11, 219.
Simoneit, B. and Mazurek: 1982, Atmos. Environ. 16, 2139.
Simoneit, B. and Mazurek: 1989, Aerosol Sci. and Tech. 10, 267.
Simoneit, B., Chester, R., and Eglinton, G.: 1977, Nature 267, 682.
Simoneit, B., Mazurek, M., and Cahill, T.: 1980, J.A.P.C.A. 30, 387.
Simoneit, B., Cox, R., and Standley, L.: 1988, Atmos. Environ. 22, 983.
Sneddon, J.: 1983, Talanta 30, 631.
Tissot, B. and Welte, D.: 1984, Petroleum Formation and Occurrence, 2nd. Edition, Springer-Verlag, Berlin.
Tramontano, J., Scudlark, J., and Church, T.: 1987, Environ. Sci. Technol. 21, 749.
Trindade, H., Pfeiffer, W., Londres, H., and Costa-Ribeiro, C.: 1981, Environ. Sci. Technol. 15, 84.
Van Vaeck, L., Broddin, G., and Van Cauwenberghe, K.: 1979, Environ. Sci. Technol. 13, 1494.
Wade, T.: 1983, Atmos. Environ. 17, 2311.
Webber, D.: 1986, Org. Geochem. 9, 57.
Westerholm, R., Stenberg, U., and Alsberg, T.: 1988, Atmos. Environ. 22, 1005.
Yamasaki, H., Kuwata, K., and Miyamoto, H.: 1982, Environ. Sci. Technol. 16, 189.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jaffé, R., Carrero, H., Cabrera, A. et al. Organic compounds and heavy metals in the atmosphere of the city of Caracas, Venezuela — I: Atmospheric particles. Water Air Soil Pollut 71, 293–313 (1993). https://doi.org/10.1007/BF00480551
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00480551