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Chemistry of Heterocyclic Compounds

, Volume 15, Issue 2, pp 158–161 | Cite as

Spectra of 3-benzoxazolonylpropanones

  • D. Simov
  • V. Kalcheva
  • B. Galabov
  • N. Markova
Article
  • 25 Downloads

Abstract

The effect of substituents on the vibrational frequencies of oxazolonyl and acetonyl carbonyl groups was studied by means of the IR and PMR spectra of a series of substituted (in the benzene ring) 3-benzoxazolonylpropanones. The experimental data and the results of correlation analysis show that the carbonyl group of the acetonyl grouping is situated along the axis perpendicular to the plane of the benzene and heterocyclic rings and the substituent. The mechanism of transmission of the effect of substituents on the characteristic frequencies and the chemical shifts of the protons of the acetonyl group in the spectra are discussed.

Keywords

Experimental Data Benzene Organic Chemistry Carbonyl Chemical Shift 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • D. Simov
    • 1
  • V. Kalcheva
    • 1
  • B. Galabov
    • 1
  • N. Markova
    • 1
  1. 1.K. Okhridskii Sofia UniversitySofiaBulgaria

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