Abstract
Combined 1H and 13C NMR data were used to show that 2-carbonyl derivatives of 1-nitrophenylpyrroles (aldehydes, acids, esters, and amides) have primarily the S-trans-configuration. Oximes of 1-nitrophenyl-2-formylpyrroles exist as a mixture of S-trans-syn- and S-cis-anti-isomers.
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Literature Cited
R. A. Jones and P. B. Gerritt, The Chemistry of Pyrroles, Academic Press, London (1977), p. 289.
P. Hodge and R. W. Rickards, J. Chem. Soc., No. 4, 2543 (1963).
V. G. Kul'nevich and é. Baum, Khim. Geterotsikl. Soedin., No. 4, 495 (1982).
C. L. Cheng, I. G. John, G. L. D. Ritchie, and P. H. Gore, J. Chem. Soc., Perkin Trans. 2, No. 11, 1318 (1974).
C. W. N. Cumper and J. W. M. Wood, J. Chem. Soc. B, No. 9, 1811 (1971).
M. Farnier and T. Drakenberg, J. Chem. Soc., Perkin Trans. 2, No. 3, 333 (1975).
B. P. Roques and S. Combrisson, Can. J. Chem., 51, 573 (1973).
G. G. Kleinspehn, J. A. Jung, and S. A. Studiarz, J. Org. Chem., 32, 460 (1967).
M. del' K. Pina, V. A. Budylin, M. Rodriges, P. B. Terent'ev, and Yu. G. Bundel', Khim. Geterotsikl. Soedin., No. 2, 180 (1989).
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Deceased.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 185–190, February, 1989.
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del', M., Pina, K., Budylin, V.A. et al. Spatial structure of derivatives of 1-nitrophenylpyrroles. Chem Heterocycl Compd 25, 146–151 (1989). https://doi.org/10.1007/BF00479907
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DOI: https://doi.org/10.1007/BF00479907