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Application of flow injection techniques for the analysis of inorganic anions

Anwendung der Fließ-Injektionsanalyse in der anorganischen Anionenanalyse

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Zusammenfassung

In tabellarischer Form wird ein Überblick über die Anwendung der Fließ-Injektionsanalyse in der anorganischen Anionenanalyse gegeben. Die Zusammenstellung enthält neben Literaturhinweisen einen kurzen Kommentar zur verwendeten Methode. Für die turbidimetrische Sulfatbestimmung wird ein Verfahren mit intermittierendem Zusatz einer Waschlösung über eine separate Pumpe vorgeschlagen. Ein Vergleich von Ergebnissen der Sulfatbestimmung mit Barium-Methylthymolblau als Reagens in Oberflächengewässern mit Ergebnissen der Ionen-Chromatographie zeigt gute Übereinstimmung. Zur Bestimmung des Sulfits wird ein Verfahren mit Hilfe der Gasdiffusion vorgestellt. Die Reproduzierbarkeit von Mehrfachinjektionen liegt, bei einer Probenfrequenz von 90 Injektionen/h, bei 1%. Das Verfahren zeichnet sich durch Unempfindlichkeit gegenüber Probeneigenfärbungen und -trübungen aus. Ergebnissen für die Bestimmung von gesamtem und freiem Sulfit in Wein, Bier und Fruchtsäften werden gegeben.

Summary

A survey of applications of flow injection analysis for the analysis of inorganic anions is given in form of a table. The turbidimetric determination of sulphate is improved by the intermittent addition of a wash solution via a separate pump. A comparison of results for the determination of sulphate in surface waters using the barium-methylthymol blue method and ion-chromatography shows good agreement. For the determination of sulphite a gas-diffusion technique is used. The method allows 90 injections/h and shows good reproducibility, 1% r.s.d. for consecutive injections of standards at the 10 mg/l SO2-level. As the sample line is physically separated from the detection line, the method is insensitive to matrix effects from coloured or turbid samples. Results for the determination of free and total sulphite in wine, beer and fruit juices are given.

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Authors and Affiliations

  1. Tecator AB, Box 70, S-263 01, Höganäs, Sweden

    J. Möller

  2. Tecator GmbH, Daimlerstr. 15-17, D-6054, Rodgau 6, Federal Republic of Germany

    B. Winter

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  1. J. Möller
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  2. B. Winter
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Lecture given at the Symposium for Inorganic Anion Analysis, Regensburg, 19.–21. 9. 1984

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Möller, J., Winter, B. Application of flow injection techniques for the analysis of inorganic anions. Z. Anal. Chem. 320, 451–456 (1985). https://doi.org/10.1007/BF00479811

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