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Chemistry of Heterocyclic Compounds

, Volume 12, Issue 3, pp 324–326 | Cite as

Determination of the three-dimensional orientation of the hydroxyl group in st ere oisomeric 1, 2, 7- trimethyl- and 1,2-dimethyl-7-tert-butyldecahydro-4-quinolols and their 4-ethynyl-substitut ed derivatives by IR spectroscopy

  • A. A. Akhrem
  • N. I. Garbuz
  • L. P. Solovei
  • L. I. Ukhova
  • A. N. Sergeeva
Article
  • 26 Downloads

Abstract

The three-dimensional orientation of the hydroxyl group in stereoisomeric 1,2,7-trimethyl- and 1,2-dimethyl-7-tert-butyldecahydro-4-quinolols and their 4-ethynyl-substituted derivatives was established by IR spectroscopy. The possibility of a twist conformation of the heteroring in 1,2,7-trimethyl- and 1,2-dimethyl-7-tert-butyldecahydro-4-quinolols with an equatorial hydroxyl group is shown.

Keywords

Spectroscopy Hydroxyl Organic Chemistry Trimethyl Twist Conformation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    E. Eliel, N. Allinger, S. Angyal, and T. Morrison, Conformational Analysis, Wiley (1965).Google Scholar
  2. 2.
    H. S. Aaron, C. P. Ferguson, and C. P. Rader, J. Amer. Chem. Soc., 89, 1431 (1967).Google Scholar
  3. 3.
    V. I. Mamonov, G. G. Dvoryantseva, T. D. Sokolova, é. B. Sysoeva, and B. V. Unkovskii, Zh. Organ. Khim., 6, 1087 (1970).Google Scholar
  4. 4.
    B. V. Unkovskii, Yu. F. Malina, I. P. Boiko, T. D. Sokolova, and M. G. Zaitseva, Zh. Organ. Khim., 3, 757 (1967).Google Scholar
  5. 5.
    R. N. Jones, P. Humphries, F. Herling, and K. Dobriner, J. Amer. Chem. Soc., 73, 3215 (1951).Google Scholar
  6. 6.
    é. A. Mistryukov and N. I. Aronov, Izv. Akad. Nauk SSSR, Ser. Khim., 789 (1967).Google Scholar
  7. 7.
    K. D. Praliev, A. A. Andrusenko, T. T. Omarov, D. V. Sokolov, L. I. Ukhova, and A. A. Akhrem, Izv. Akad. Nauk KazSSR, Ser. Khim., 49 (1967).Google Scholar
  8. 8.
    C. Y.Chen and R.I.W. LeFevre.J.Chem.Soc., B, 539 (1966).Google Scholar
  9. 9.
    A. A. Akhrem, L. I. Ukhova, and A. N. Sergeeva, Izv. Akad. Nauk BelSSR, Ser. Khim., No. 4, 53 (1975); No. 5, (1975); No. 6, 66, 75 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • A. A. Akhrem
    • 1
  • N. I. Garbuz
    • 1
  • L. P. Solovei
    • 1
  • L. I. Ukhova
    • 1
  • A. N. Sergeeva
    • 1
  1. 1.Institute of Bioorganic ChemistryAcademy of Sciences of the Belorussian SSRMinsk

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