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1,3-Dipolar cycloaddition of 2-benzylideneindan-1,3-dione α-oxide to olefins

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A carbonyl ylid, which reacts with maleic anhydride, N-phenylmaleinimide, and Β-nitrostyrene to form adducts resulting from 1,3-dipolar cycloaddition, is formed reversibly when 2-benzylideneindan-1,3-dione α-oxide is heated (80‡C). The reaction proceeds regio- and stereospecifically.

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Authors and Affiliations

  1. Lenin Komsomol Voronezh State University, 394696, Voronezh

    M. Yu. Krysin, I. K. Anokhina & L. P. Zalukaev

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  1. M. Yu. Krysin
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  2. I. K. Anokhina
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  3. L. P. Zalukaev
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1463–1466, November, 1987.

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Krysin, M.Y., Anokhina, I.K. & Zalukaev, L.P. 1,3-Dipolar cycloaddition of 2-benzylideneindan-1,3-dione α-oxide to olefins. Chem Heterocycl Compd 23, 1166–1169 (1987). https://doi.org/10.1007/BF00479360

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  • DOI: https://doi.org/10.1007/BF00479360

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