Chemistry of Heterocyclic Compounds

, Volume 24, Issue 8, pp 877–879 | Cite as

9-alkenylcarbazoles. 13. Trifluoroacetylation of trans- and cis-9-alkenylcarbazoles

  • N. V. Moskalev
  • V. D. Filimonov
  • E. E. Sirotkina


The trifluoroacetylation of 9-alkenylcarbazoles in pyridine takes place regio- and stereospecifically with the formation of the Β-trifluoroacetyl derivatives. The cis isomers are inert to trifluoroacetic anhydride.


Organic Chemistry Pyridine Anhydride Trifluoroacetic Anhydride 
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Literature Cited

  1. 1.
    V. A. Anfinogenov, N. N. Malkova, E. E. Sirotkina, and V. D. Filimonov, Zh. Org. Khim., 22, 2403 (1986).Google Scholar
  2. 2.
    M. Hojo, R. Masuda, Y. Kokurio, H. Shioda, and S. Matsuo, Chem. Lett., No. 5, 499, (1976).Google Scholar
  3. 3.
    M. Hojo, R. Masuda, and V. Kamitorov, Tetrahedron Lett., 17, 1009 (1976).Google Scholar
  4. 4.
    B. A. Trofimov and A. I. Mikhaleva, N-Vinylpyrroles [in Russian], Nauka, Novosibirsk (1984), p. 127.Google Scholar
  5. 5.
    V. D. Filimonov, V. A. Anfinogenov, and E. E. Sirotkina, Zh. Org. Khim., 14, 2550 (1978).Google Scholar
  6. 6.
    V. G. Rozinov, G. A. Pensionerova, V. I. Donskikh, L. M. Sergienko, S. E. Korostova, A. I. Mikhaleva, and G. V. Dolgushin, Zh. Obshch. Khim., 56, 790 (1986).Google Scholar
  7. 7.
    V. D. Filimonov, V. A. Anfinogenov, and S. G. Gorbachev, Khim. Geterotsikl. Soedin., No. 12, 1640 (1982).Google Scholar
  8. 8.
    J. Schraml, Collection, No. 10, 3063 (1976).Google Scholar
  9. 9.
    V. D. Filimonov, V. A. Anfinogenov, and E. E. Sirotkina, Zh. Org. Khim., 14, 2607 (1978).Google Scholar
  10. 10.
    C. L. Bumgardner, J. E. Bunch, and M.-H., Whangdo, Tetrahedron Lett., 27, 1883 (1986).Google Scholar
  11. 11.
    V. D. Filimonov, S. G. Gorbachev, and E. E. Sirotkina, J. Org. Chem., No. 3, 340 (1980).Google Scholar
  12. 12.
    E. E. Sirotkina, N. V. Moskalev, and I. G. Shabotkin, Khim. Geterotsikl. Soedin., No. 5, 640 (1984).Google Scholar

Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • N. V. Moskalev
    • 1
    • 2
  • V. D. Filimonov
    • 1
    • 2
  • E. E. Sirotkina
    • 1
    • 2
  1. 1.Institute of Petroleum Chemistry, Siberian BranchAcademy of Sciences of the USSRTomsk
  2. 2.S. M. Kirov Tomsk Polytechnical InstituteUSSR

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