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Chemistry of Heterocyclic Compounds

, Volume 24, Issue 4, pp 387–394 | Cite as

2-Aziridino- and 2-diaziridino-3,3-bis(trifluoromethyl)aziridines

  • R. G. Kostyanovskii
  • G. K. Kadorkina
  • S. V. Varlamov
  • I. I. Chervin
  • I. K. A. Romero-Maldonado
Article
  • 26 Downloads

Abstract

3,3-Bis(trifluoromethyl)-1-azirine, formed by the reaction of 1-arenesulfonyloxy-2,2-bis(trifluoromethyl)aziridines with nucleophilic reagents, reacts with aliphatic amines with ring-opening and formation of formamidines. With aziridines and diaziridines having a lower electron-donor capability of the nitrogen atom, it forms the adducts -2-aziridino- and -2-diaziridino-3,3-bis(trifluoromethyl)aziridines. All the isomers theoretically possible were recorded for these derivitives by the dynamic NMR method.

Keywords

Nitrogen Organic Chemistry Adduct Nitrogen Atom Trifluoromethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • R. G. Kostyanovskii
    • 1
  • G. K. Kadorkina
    • 1
  • S. V. Varlamov
    • 1
  • I. I. Chervin
    • 1
  • I. K. A. Romero-Maldonado
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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