Chemistry of Heterocyclic Compounds

, Volume 24, Issue 4, pp 387–394 | Cite as

2-Aziridino- and 2-diaziridino-3,3-bis(trifluoromethyl)aziridines

  • R. G. Kostyanovskii
  • G. K. Kadorkina
  • S. V. Varlamov
  • I. I. Chervin
  • I. K. A. Romero-Maldonado


3,3-Bis(trifluoromethyl)-1-azirine, formed by the reaction of 1-arenesulfonyloxy-2,2-bis(trifluoromethyl)aziridines with nucleophilic reagents, reacts with aliphatic amines with ring-opening and formation of formamidines. With aziridines and diaziridines having a lower electron-donor capability of the nitrogen atom, it forms the adducts -2-aziridino- and -2-diaziridino-3,3-bis(trifluoromethyl)aziridines. All the isomers theoretically possible were recorded for these derivitives by the dynamic NMR method.


Nitrogen Organic Chemistry Adduct Nitrogen Atom Trifluoromethyl 
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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • R. G. Kostyanovskii
    • 1
  • G. K. Kadorkina
    • 1
  • S. V. Varlamov
    • 1
  • I. I. Chervin
    • 1
  • I. K. A. Romero-Maldonado
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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