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Herbicidal hydroxylamine derivatives

XL. Energy of intermolecular hydrogen bonding and structure of the associates of o-methylhydroxylamine derivatives of sym-triazines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The energies of intermolecular hydrogen bonding for eight amino derivatives of sym-triazines were obtained from the temperature dependence of the equilibrium constants, which were determined by ebullioscopic and cryoscopic methods. It is shown that the investigated compounds form cyclic, centrosymmetrical dimers under the influence of hydrogen bonds. The nitrogen in the 1 or 5 position of the ring is a proton acceptor.

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Authors and Affiliations

  1. All-Union Scientific-Research Institute of Chemical Agents for Plant Protection, Moscow

    P. V. Tibanov, A. F. Vasil'ev, Yu. A. Baskakov, B. N. Levinskii & I. A. Mel'nikova

Authors
  1. P. V. Tibanov
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  2. A. F. Vasil'ev
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  3. Yu. A. Baskakov
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  4. B. N. Levinskii
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  5. I. A. Mel'nikova
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Additional information

See [1] for communication XXXIX.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 124–128, January, 1972.

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Tibanov, P.V., Vasil'ev, A.F., Baskakov, Y.A. et al. Herbicidal hydroxylamine derivatives. Chem Heterocycl Compd 8, 115–118 (1972). https://doi.org/10.1007/BF00478506

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  • DOI: https://doi.org/10.1007/BF00478506

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