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N-arylpyrrolidones

II. Chloromethylation of N-phenylpyrrolidone and some transformations of its chloromethyl derivative

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The chloromethylation of N-phenylpyrrolidone proceeds at the paraposition of the benzene ring. The reactivity of the chloromethyl group in reactions with ammonium thiocyanate, potassium ethylxanthate, sodium acetate, thiourea, potassium phthalimide, urotropine, sodium thiosulfate, and potassium permanganate was investigated. A number of previously undescribed compounds, of which some were found to be active pesticides, were synthesized.

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Literature cited

  1. S. S. Kukalenko and N. A. Gracheva, Khim. Geterotsikl. Soedin., 773 (1971).

  2. Bo Gestblom, R. A. Hoffman, and S. Rodmar, Mol. Phys., 8, 425 (1964).

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  3. Bo Gestblom, R. A. Hoffman, and S. Rodmar, Acta Chem. Scand., 13, 1222 (1964).

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Authors and Affiliations

  1. All-Union Scientific-Research Institute of Chemical Agents for the Protection of Plants, Moscow

    S. S. Kukalenko & V. I. Sukhodolova

Authors
  1. S. S. Kukalenko
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  2. V. I. Sukhodolova
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 45–47, January, 1972.

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Kukalenko, S.S., Sukhodolova, V.I. N-arylpyrrolidones. Chem Heterocycl Compd 8, 43–45 (1972). https://doi.org/10.1007/BF00478489

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  • DOI: https://doi.org/10.1007/BF00478489

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