Chemistry of Heterocyclic Compounds

, Volume 4, Issue 1, pp 110–111 | Cite as

The oxidation of organic compounds

XLIX. The vapor phase catalytic oxidation of tris(hydroxymethyl)-4-picoline
  • T. A. Afanas'eva
  • A. D. Kagarlitskii
  • B. V. Suvorov
Article
  • 25 Downloads

Abstract

In a study of the behavior of tris(hydroxymethyl)-4-picoline (I) under the conditions of vapor-phase oxidation on a vanadium-tin oxide catalyst, it was found that with the addition of 150–250 mole of water and 125–200 mole of O2 per mole of I and a contact time of 0.35–0.45 sec, the main reaction product was isonicotinic acid (II), the yield of which amounted to 60–65% of theoretical, calculated on the I passed.

Keywords

Oxidation Organic Chemistry Organic Compound Contact Time Hydroxymethyl 

References

  1. 1.
    B. V. Suvorov, A. A. Shapovalov, D. Kh. Sembaev, and L. P. Pogrebnaya, Vestn. AN Kaz. SSR, [in press].Google Scholar
  2. 2.
    R. W. Lewis and O. W. Brown, Ind. Eng. Chem., 36, 890, 1944.Google Scholar
  3. 3.
    F. E. Cislak and W. R. Wheeler, US Patent 2437938, 1948, C. A., 42, 4204, 1948.Google Scholar
  4. 4.
    T. Ishiguro, J. Pharm. Soc. Japan, 72, 709, 1952; 1425; C. A., 47, 2174, 8069, 1953.Google Scholar
  5. 5.
    M. Yu. Lidak, S. A. Hiller, and N. N. Naumenko, Izv. AN Latv SSR, ser. khim., 12, 83, 1953.Google Scholar
  6. 6.
    B. V. Suvorov, S. R. Rafikov, and M. I. Khmura, Izv. AN Kaz. SSR, ser. khim., no. 1 (15), 80, 1959.Google Scholar
  7. 7.
    V. S. Kudinova, S. R. Rafikov, K. D. Sagintaeva, and B. V. Suvorov, ZhPKh, 35, 2313, 1962.Google Scholar
  8. 8.
    W. Koenigs and G. Happe, Ber., 36, 2904, 1903.Google Scholar
  9. 9.
    A. B. Beloslyudov, D. Kh. Sembaev, and B. V. Suvorov, Zav. lab., no. 5, 621, 1961.Google Scholar
  10. 10.
    P. C. Tompkins and C. L. A. Schmidt, Univ. California Publ. Physiol., 8, 221, 1943.Google Scholar

Copyright information

© The Faraday Press, Inc. 1970

Authors and Affiliations

  • T. A. Afanas'eva
    • 1
  • A. D. Kagarlitskii
    • 1
  • B. V. Suvorov
    • 1
  1. 1.Institute of Chemical SciencesAS Kazakh SSRAlma-Ata

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