Chemistry of Heterocyclic Compounds

, Volume 7, Issue 1, pp 86–89 | Cite as


V. Chlorination of 2,3-polymethylenequinolines with phosphorus pentachloride
  • L. E. Kholodov
  • N. M. Merzlyakova
  • N. P. Kostyuchenko
  • M. N. Shchukina


Β-Quinindane and tetrahydroacridine derivatives are chlorinated at the methylene groups of the hydrogenated ring under the influence of phosphorus pentachloride. Two, three, or five hydrogen atoms are replaced by chlorine, depending on the substituent in the 9 position and the size of the polymethylene chain. The structures of the compounds obtained were confirmed by IR, UV, and PMR spectra.


Hydrogen Methylene Phosphorus Organic Chemistry Polymethylene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    L. E. Kholodov and V. G. Yashunskii, Khim. Geterotsikl. Soedin., 1530 (1970).Google Scholar
  2. 2.
    K. Nakanishi, Infrared Spectra and Structure of Organic Compounds [Russian translation], Moscow (1965), p. 196.Google Scholar
  3. 3.
    I. Braun and G. Kirschbaum, Ber., 54, 602, 617 (1921).Google Scholar
  4. 4.
    B. K. Blount, J. Chem. Soc., 553 (1933).Google Scholar
  5. 5.
    B. K. Blount, W. H. Perkin, and S. G. Plant, J. Chem. Soc., 1975 (1929).Google Scholar
  6. 6.
    H. Tiedke, Ber., 42, 624 (1909).Google Scholar
  7. 7.
    B. K. Blount and S. G. Plant, J. Chem. Soc., 376 (1937).Google Scholar
  8. 8.
    L. E. Kholodov, G. P. Syrova, V. G. Yashunskii, and Yu. N. Sheinker, Khim. Geterotsikl. Soedin., 78 (1970).Google Scholar
  9. 9.
    W. Borsche, Ann., 377, 120 (1910).Google Scholar
  10. 10.
    I. F. Tishchenkova, L. E. Kholodov, and V. G. Yashunskii, Khim. Geterotsikl. Soedin., 87 (1971).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • L. E. Kholodov
    • 1
  • N. M. Merzlyakova
    • 1
  • N. P. Kostyuchenko
    • 1
  • M. N. Shchukina
    • 1
  1. 1.S. Ordzhonikidze All-Union Scientific-Research Pharmaceutical Chemistry InstituteMoscow

Personalised recommendations