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Synthesis and three-dimensional structures of the cis and trans isomers of 3-methyl-1-tert-butyl-4-acetyl- and 3-methyl-1-tert-butyl-4-carbomethoxy-4-piperidols

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The cis and trans isomers of 3-methyl-1-tert-butyl-4-acetyl- and 3-methyl-1-tertbutyl-4-carbomethoxy-4-piperidols, the three-dimensional configurations of which were established by means of their IR and UV spectra, were synthesized in order to study the interrelationship between the structure and reactivity of stereoisomeric piperidines.

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Translated from Khimiya Geterotsiklicheskikh Soedinenni, No.12, pp. 1659–1665, December, 1973.

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Unkovskii, B.V., Sokolova, T.D., Malina, Y.F. et al. Synthesis and three-dimensional structures of the cis and trans isomers of 3-methyl-1-tert-butyl-4-acetyl- and 3-methyl-1-tert-butyl-4-carbomethoxy-4-piperidols. Chem Heterocycl Compd 9, 1501–1506 (1973). https://doi.org/10.1007/BF00477566

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  • DOI: https://doi.org/10.1007/BF00477566

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