Chemistry of Heterocyclic Compounds

, Volume 9, Issue 12, pp 1453–1455 | Cite as

Stereochemistry of bisdioxolane systems

I. Synthesis and configuration of isomers of 1,2-bis[4-(p-tosyloxymethyl)-1,3-dioxolan-2-yl]ethane
  • G. P. Sokolov
  • S. A. Giller


A number of diastereomers of cyclic diacetals of succinaldehyde were obtained by transacetalation of succinaldehyde bis(dimethylacetal) with the optical antipodes of tosylglycerol. The configurations of the products were determined.


Organic Chemistry Dimethylacetal Optical Antipode Succinaldehyde 
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Literature cited

  1. 1.
    G. P. Sokolov, M. G. Voronkov, and S. A. Giller, Izv. Akad. Nauk LatvSSR, Ser. Khim., 667 (1964).Google Scholar
  2. 2.
    G. P. Sokolov, V. E. Klusha, A. A. Kimenis, and S. A. Giller, Khim.-Farmats. Zh., No. 3, 3 (1968).Google Scholar
  3. 3.
    G. P. Sokolov, S. A. Giller, A. A. Kimenis, V. E. Klusha, and Ya. Ya. Ginters, USSR Author's Certificate No. 278, 963 (1969); Byull. Izobr., No. 26, 82 (1970).Google Scholar
  4. 4.
    N. Baggett, I. M. Duxbury, A. B. Foster, and I. M. Webber, J. Chem. Soc., 208 (1966).Google Scholar
  5. 5.
    G. P. Sokolov, R. O. Vitolin', and S. A. Giller, Khim.-Farmats. Zh. (in press).Google Scholar
  6. 6.
    R. U. Lemieux, in: Molecular Rearrangements (edited by P. de Mayo), Vol. 2, Interscience (1964), p. 728.Google Scholar
  7. 7.
    D. I. Triggle and B. Belleu, Can. J. Chem., 40, 1201 (1962).Google Scholar
  8. 8.
    B. Belleu and I. Purenen, J. Med. Chem., 6, 325 (1963).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • G. P. Sokolov
    • 1
  • S. A. Giller
    • 1
  1. 1.Institute of Organic SynthesisAcademy of Sciences of the Latvian SSRRiga

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