Abstract
The direction taken by the reaction of α-hydroxylaminooximes (prepared by the action of hydroxylamine on α -halogenoketones) with aldehydes depends on the geometric configuration of the oxime group, cis isomers reacting with benzaldehyde to give N -substituted α -phenylnitrones and with acetaldehyde to give derivatives of 4H-1, 2, 5-oxadiazine. Anti-α-hydroxylaminooxime and acetaldehyde give substituted 1 -hydroxy-3-imidazolin-3-oxide. The structures of the compounds synthesized check by analyses of their UV and IR spectra.
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For Part VI see [1].
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Volodarskii, L.B., Lysak, A.N. & Koptyug, V.A. Chemistry of α -hydroxylaminooximes. Chem Heterocycl Compd 2, 591–596 (1966). https://doi.org/10.1007/BF00477528
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DOI: https://doi.org/10.1007/BF00477528