Chemistry of Heterocyclic Compounds

, Volume 2, Issue 5, pp 532–534 | Cite as

Catalytic reduction of 2-thiophenaldehyde and 2-acetothienone

  • M. A. Ryashentseva
  • O. A. Kalinovskii
  • Kh. M. Minachev
  • Ya. L. Gol'dfarb
Article

Abstract

A catalyst, rhenium heptasulfide, has been found for reducing 2-thiophenaldehyde and 2-acetylthiophene to the corresponding alkylthiophenes. The reduction conditions found were: temperature 170° -190° C, hydrogen pressure 130 atm, time 3–6 hr. Reduction of 2-thiophenaldehyde in methanol in the presence of rhenium heptasulfide gives 2-methoxythiphene, while corresponding hydrogenation of 2-acetylthiophene in ammonia plus dioxane gives 2-(α -aminoethyl) thiophene.

Keywords

Hydrogen Methanol Ammonia Organic Chemistry Dioxane 

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Copyright information

© The Faraday Press, Inc. 1968

Authors and Affiliations

  • M. A. Ryashentseva
    • 1
  • O. A. Kalinovskii
    • 1
  • Kh. M. Minachev
    • 1
  • Ya. L. Gol'dfarb
    • 1
  1. 1.Zelinskii Institute of Organic ChemistryAS USSRMoscow

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