Advertisement

Chemistry of Heterocyclic Compounds

, Volume 8, Issue 4, pp 408–411 | Cite as

Investigations of polyfunctional oxides

V. PMR spectra, configurations, and conformations of 2,2,4-trialkyl-5-(2-carboalkoxyvinyl)-1,3-dioxolanes and 2,2,4-trialkyl-5-(2-carboalkoxyethyl)-1,3-dioxolanes
  • Yu. Yu. Samitov
  • L. P. Glushko
  • M. S. Malinovskii
  • N. I. Pokhodenko
Article
  • 25 Downloads

Abstract

The reaction of esters of 4,5-epoxy-2-hexenoic acid with ketones in the presence of acid catalysts gives 2,2,4-trialkyl-5-(2-carboalkoxyvinyl)-1,3-dioxolanes, the hydrogenation of which gives the corresponding saturated dioxolanes. The conformations and configurations of the dioxolanes obtained were studied by means of their PMR spectra.

Keywords

Oxide Hydrogenation Ester Organic Chemistry Ketone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    L. P. Glushko, N. I. Pokhodenko, M. S. Malinovskii, and É. G. Sumbaev, Zh. Organ. Khim., 7, 1591 (1971).Google Scholar
  2. 2.
    M. S. Malinovskii, L. P. Glushko, N. I. Pokhodenko, L. I. Kopeiko, and V. I. Avramenko, in: Chemical Structure, Properties, and Reactivities of Organic Compounds [in Russian], Kiev (1969), p. 71.Google Scholar
  3. 3.
    A. A. Bothner-By, Advances in Magnetic Resonance, New York-London, Vol. 1 (1965), p. 195.Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • Yu. Yu. Samitov
    • 1
    • 2
  • L. P. Glushko
    • 1
    • 2
  • M. S. Malinovskii
    • 1
    • 2
  • N. I. Pokhodenko
    • 1
    • 2
  1. 1.Dnepropetrovsk State UniversityUSSR
  2. 2.Kazan State UniversityUSSR

Personalised recommendations