Skip to main content
SpringerLink
Log in

Dioxolanium salts

Synthesis and reactions with some nucleophilic reagents

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A new method was developed for the synthesis of dioxolanium salts by the condensation of 1,2-glycols of the pinacol series with aliphatic acid anhydrides in the presence of perchloric acid. The dioxolanium ring is opened to form monoacylates of the starting pinacols under the influence of water, alcohol, and ammonia. A method was developed for the acetylation of aromatic compounds by dioxolanium salts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. H. Meerwein, K. Bodenbenner, P. Borner, F. Kunert, and K. Wunderlish, Lieb. Ann., 632, 38 (1960).

    Google Scholar 

  2. H. Meerwein, V. Hederish, H. Morschel, and K. Wunderlish, Lieb. Ann., 635, 1 (1960).

    Google Scholar 

  3. H. Meerwein and K. Wunderlish, Angew. Chem., 69, 481 (1957).

    Google Scholar 

  4. G. N. Dorofeenko and L. V. Mezheritskaya, Zh. Obshch. Khim., 38, 1192 (1968).

    Google Scholar 

  5. Bergmann and Pinchas, Rec. Trav. Chim., 71, 161 (1952).

    Google Scholar 

  6. L. S. Povarov, Usp. Khim., 34, 1491 (1965).

    Google Scholar 

  7. V. V. Mezheritskii and G. N. Dorofeenko, Zh. Organ. Khim., 3, 1533 (1967).

    Google Scholar 

  8. V. V. Mezheritskii and G. N. Dorofeenko, Khim. Geterotsikl. Soedin., No. 2, 232 (1970).

    Google Scholar 

  9. G. N. Dorofeenko, Yu. A. Zhdanov, V. I. Dulenko, and S. V. Krivun, Perchloric Acid and Its Compounds in Organic Synthesis [in Russian], Izd. Rost. Univ., (1965), pp. 47, 53.

  10. S. V. Krivun, Dokl. Akad. Nauk SSSR, 180, 615 (1968).

    Google Scholar 

  11. Dictionary of Organic Compounds, Oxford University Press (1966).

Download references

Author information

Authors and Affiliations

  1. Rostov-on-Don State University, USSR

    L. V. Mezheritskaya & G. N. Dorofeenko

Authors
  1. L. V. Mezheritskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. N. Dorofeenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1023–1026, August, 1971.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mezheritskaya, L.V., Dorofeenko, G.N. Dioxolanium salts. Chem Heterocycl Compd 7, 959–962 (1971). https://doi.org/10.1007/BF00477370

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00477370

Keywords

Search

Navigation