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Chemistry of Heterocyclic Compounds

, Volume 12, Issue 12, pp 1343–1347 | Cite as

Reaction of tetracyanoquinodimethane with azoles

  • B. P. Bespalov
  • E. V. Getmanova
  • A. A. Pankratov
  • V. V. Titov
Article
  • 29 Downloads

Abstract

The reaction of tetracyanoquinodimethane (TCQD) with azoles was studied. It was found that products of 1,6 addition to the quinoid system of TCQD are formed with pyrrole, indole, and their methyl derivatives. The addition products split out HCN under the influence of UV light to give deeply colored products of replacement of one nitrile group in TCQD by a heterocyclic grouping. Data on the UV and NMR spectra of the compounds obtained are presented.

Keywords

Methyl Organic Chemistry Nitrile Indole Pyrrole 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • B. P. Bespalov
    • 1
  • E. V. Getmanova
    • 1
  • A. A. Pankratov
    • 1
  • V. V. Titov
    • 1
  1. 1.Scientific-Research Institute of Organic Intermediates and DyesMoscow

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