Abstract
2-Amino-4,6-disubstituted-sym-triazines containing sterically hindered phenol segments were synthesized by cyclocondensation of N-acrylguanidines with nitriles or thiocyanates. The same compounds can be obtained by condensation of N-acylguanidine with iminoester hydrochlorides. The reaction of methyl Β-(4-hydroxy-3,5-di-tert-butylphenyl)propionate with biguanides gives N-substituted 2,4-diamino-6-R-sym-triazines that contain a shielded phenol residue.
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For Communication 5, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1392–1397, October, 1987.
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Kelarev, V.I., Yakh'ya, F.L., Karakhanov, R.A. et al. Synthesis and properties of sym-triazine derivatives. 6. Synthesis of 2-amino- and 2,4-diamino-sym-triazines containing sterically hindered phenol segments. Chem Heterocycl Compd 23, 1118–1123 (1987). https://doi.org/10.1007/BF00476544
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DOI: https://doi.org/10.1007/BF00476544