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Chemistry of Heterocyclic Compounds

, Volume 23, Issue 5, pp 558–562 | Cite as

The nature of the inductive effect of azinyl groups

  • O. P. Shkurko
  • V. P. Mamaev
Article

Abstract

The induction constants of azinyl groups are factored into two components, a σ-induction (σ X ) and a field (σF) component. It is shown that the σ X constants of azinyl groups can be thought of as sums of contributions from the phenyl group and the endocyclic nitrogen atoms. A satisfactory correlation is found between the σF constants and the size and direction of the dipole moment of the heterocyclic substituents in the framework of the Kirkwood-Westheimer equation.

Keywords

Nitrogen Organic Chemistry Phenyl Dipole Moment Nitrogen Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • O. P. Shkurko
    • 1
  • V. P. Mamaev
    • 1
  1. 1.Novosibirsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRNovosibirsk

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