Abstract
Reaction of the syn isomers of α-hydroxylaminooximes with nitrobenzene gives α-azoxy-oximes, which undergo intramolecular cyclization to 2H-1,2,3-triazole N-oxide derivatives under the influence of hydrogen chloride.
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L. B. Volodarskii and A. N. Lysak, Khim. Geterotsikl. Soedin., 904 (1967).
J. N. Brough, B. Lythgoe, and P. Waterhouse, J. Chem. Soc., 4069 (1954).
J. P. Freeman, J. Org. Chem., 28, 2508 (1963).
Beilst., H 26, 70.
G. Ponzio, J. Prakt. Chem., 57, 164 (1898).
B. V. Ioffe, Z. I. Sergeeva, and V. S. Stopskii, Dokl. Akad. Nauk SSSR, 831 (1966).
E. L. Scott and F. J. Lalor, Chem. and Ind., 420 (1966).
A. Kolb, Liebigs Ann., 291, 280 (1896).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 131–133, January, 1973.
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Amitina, S.A., Volodarskii, L.B. Conversion of α-azoxyoximes to 2H-1,2,3-triazole N-oxide derivatives. Chem Heterocycl Compd 9, 120–122 (1973). https://doi.org/10.1007/BF00476168
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DOI: https://doi.org/10.1007/BF00476168