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Correlation between the mass-spectrometric behavior and chromatographic mobility of epimeric 4-alkyl-1,2-dimethyl-trans-perhydroquinolol N-oxides

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The dependence between the Chromatographic mobility, the character of the disintegration under electron impact, and the configuration at C(4) was found for epimeric N-oxides of 1,2-dimethyl-4-ethyl-,-4-vinyl-, and -4-ethynylperhydro-4-quinolols. It Is proposed that this dependence be used to determine the configuration at C(4) in 1,4-dialkyl-trans-perhydro-4-quinolols, from which two epimeric N-oxides can be obtained.

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Literature cited

  1. V. G. Zaikin, N. S. Vul'fson (Wulfson), V. I. Zaretskii, A. A. Bakaev, A. A. Akhrem, L. I. Ukhova, and N. F. Uskova, Organic Mass Spectrometry, 2, 1257 (1969).

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Authors and Affiliations

  1. M. M. Shemyakin Insitute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR, Moscow

    N. S. Vul'fson, V. G. Zaikin, A. A. Bakaev, A. A. Akhrem, L. I. Ukhova & N. F. Marchenko

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. S. Vul'fson, V. G. Zaikin, A. A. Bakaev, A. A. Akhrem, L. I. Ukhova & N. F. Marchenko

  3. Institute of Physical Organic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk

    N. S. Vul'fson, V. G. Zaikin, A. A. Bakaev, A. A. Akhrem, L. I. Ukhova & N. F. Marchenko

Authors
  1. N. S. Vul'fson
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  2. V. G. Zaikin
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  3. A. A. Bakaev
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  4. A. A. Akhrem
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  5. L. I. Ukhova
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  6. N. F. Marchenko
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 74–76, January, 1973.

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Vul'fson, N.S., Zaikin, V.G., Bakaev, A.A. et al. Correlation between the mass-spectrometric behavior and chromatographic mobility of epimeric 4-alkyl-1,2-dimethyl-trans-perhydroquinolol N-oxides. Chem Heterocycl Compd 9, 63–65 (1973). https://doi.org/10.1007/BF00476152

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  • DOI: https://doi.org/10.1007/BF00476152

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