Abstract
The reaction of bis (trifluoromethyl)ketene with bis(trifluoromethyl)methionic anhydride at 200°C has given hexafluorothioacetone dioxide trimer; 2,2,3,3-tetrakis (trifluoromethyl)thiirane 1,1-dioxide is formed as a byproduct. The same trimer is obtained by heating hexafluoroisobutenylidene sulfate and by treating hexafluoro-αH-isobutyric acid with sulfur trioxide.
Similar content being viewed by others
Literature cited
V. M. Pavlov, V. N. Dergachev, G. A. Sokol'skii, and I. L. Knunyants, Khim. Geterotsikl. Soedin., 1321 (1973).
G. Opitz, Angew. Chem., 78, 1066 (1966).
W. J. Middleton, U.S. Patent No. 3,136,781 (1964); Chem. Abstr., 61, 5612 c (1964).
K. V. Martin, J. Chem. Soc., 2944 (1964).
E. Eliel, N. Allinger, S. Angyal, and G. Morrison, Conformational Analysis, Interscience (1965), Chap. 2.
O. Hassel and H. Viervoll, Acta Chem. Scand., 1, 149 (1947).
M. Kimura and K. Aoki, J. Chem. Soc. Japan, 72, 169 (1951).
L. E. Sutton, Tables of Interatomic Distances and Configuration, Chemical Society Special Publication, No. 11, London (1958).
V. M. Pavlov, M. A. Belaventsev, V. F. Gorelov, G. A. Sokol'skii, and I. L. Knunyants, Khim. Geterotsikl. Soedin., 13 (1973).
Author information
Authors and Affiliations
Additional information
For Communication V, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 42–44, January, 1974.
Rights and permissions
About this article
Cite this article
Sokol'skii, G.A., Pavlov, V.M., Golovkin, V.M. et al. Fluorosulfonyl-containing heterocyclic compounds. Chem Heterocycl Compd 10, 34–36 (1974). https://doi.org/10.1007/BF00475903
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00475903