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Fluorosulfonyl-containing heterocyclic compounds

VI. Hexafluorothioacetone dioxide trimer

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of bis (trifluoromethyl)ketene with bis(trifluoromethyl)methionic anhydride at 200°C has given hexafluorothioacetone dioxide trimer; 2,2,3,3-tetrakis (trifluoromethyl)thiirane 1,1-dioxide is formed as a byproduct. The same trimer is obtained by heating hexafluoroisobutenylidene sulfate and by treating hexafluoro-αH-isobutyric acid with sulfur trioxide.

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For Communication V, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 42–44, January, 1974.

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Sokol'skii, G.A., Pavlov, V.M., Golovkin, V.M. et al. Fluorosulfonyl-containing heterocyclic compounds. Chem Heterocycl Compd 10, 34–36 (1974). https://doi.org/10.1007/BF00475903

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  • DOI: https://doi.org/10.1007/BF00475903

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