Chemistry of Heterocyclic Compounds

, Volume 10, Issue 1, pp 27–29 | Cite as

Investigations in the field of vinyl esters of the furan series

XI. Investigation of the kinetics of the alkaline hydrolysis of vinyl esters of acids of the furan series by a polarographic method
  • G. G. Skvortsova
  • Yu. A. Mansurov
  • N. M. Deriglazov
Article
  • 25 Downloads

Abstract

The kinetics of the alkaline hydrolysis of vinyl esters of furan-2-carboxylic, trans-β-(2-furyl)acrylic, and trans-cinnamic acids and also the comparative electrochemical activities of these compounds and of vinyl esters of 5-bromofuran-2-carboxylic, 5-nitro-furan-2-carboxylic, and benzoic acids have been studied by a polarographic method. A symbatic increase in the rate of hydrolysis of the esters with a shift of the potential of the half-wave of reduction into the more negative region has been established. Both the polarity and the polarizability of the molecules have a fundamental influence on the properties of the esters.

Keywords

Ester Hydrolysis Organic Chemistry Vinyl Negative Region 

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • G. G. Skvortsova
    • 1
  • Yu. A. Mansurov
    • 1
  • N. M. Deriglazov
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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