Abstract
High-dilution azocoupling of bisdiazotized bis-(2-aminophenyl)oligooxa (orthia)alkanes with resorcinol gives tetraazamacrocycles with two endocyclic azo-groups. It is shown that azocoupling occurs exclusively at the 2- and 4-positions of the resorcinol ring.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 126–130, January, 1988.
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Sultanov, A.V., Savvin, S.B. Macroheterocycles with an endocyclic azo-group. 1. Tetraazamacrocycles obtained from resorcinol. Chem Heterocycl Compd 24, 106–109 (1988). https://doi.org/10.1007/BF00475582
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DOI: https://doi.org/10.1007/BF00475582