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Catalytic hydroamination of furfuryl and tetrahydrofurfuryl alcohols with nitriles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Reaction of furfuryl and tetrahydrofurfuryl alcohols with nitriles over copper oxide catalysts under a hydrogen pressure of 15 atm at a temperature of 230‡C gives N-alkylfurfuryl- (yield 46–50%) and N-alkyl-tetrahydrofurfurylamines (49–53%), and N-alkylpiperidines (28–41%). A reaction mechanism is proposed.

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Literature Cited

  1. Murohashi Susumu, Res. Repts. Nagaoka, Tech. Coll., No. 2, 113 (1972); Ref. Zh. Khim., 2Zh270 (1973).

    Google Scholar 

  2. L. Zafiriadis and P. Mestagli, Compts. Rendu, No. 3, 295 (1953).

    Google Scholar 

  3. G. E. Abgaforov, N. I. Shuikin, and I. F. Bel'skii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 734 (1965).

    Google Scholar 

  4. N. S. Kozlov, L. I. Moiseenok, and S. I. Kozintsev, Dokl. Akad. Nauk SSSR, 252, 1132 (1980).

    Google Scholar 

  5. Yu. K. Yur'ev and E. G. Vendel'shtein, Uch. Zap. Mosk. Gos. Univ., No. 151, 221 (1951).

    Google Scholar 

  6. Belgian Pat. No. 628 646; Chem. Abstr., 61, 13288h (1964).

  7. Yu. K. Yur'ev, Uch. Zap. Mosk. Gos. Univ., No. 175, 159 (1956).

    Google Scholar 

  8. A. N. Bashkirov, G. A. Kliger, O. A. Lesik, é. V. Marchevskaya, and L. S. Glebov, Kinet. Katal., No. 2, 392 (1983).

    Google Scholar 

  9. N. S. Kozlov, L. I. Moiseenok, and S. I. Kozintsev, Izv. Akad. Nauk Bulg. SSR, Ser. Khim., No. 6, 25 (1980).

    Google Scholar 

  10. B. P. Nikol'skii (ed.), Chemists Handbook [in Russian], Khimiya, Moscow, Leningrad (1966), Vol. 2, p. 465.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry, Academy of Sciences of the Belorussian SSR, 220603, Minsk

    S. I. Kozintsev, L. I. Basalaeva, L. V. Gladkikh & N. S. Kozlov

Authors
  1. S. I. Kozintsev
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  2. L. I. Basalaeva
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  3. L. V. Gladkikh
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  4. N. S. Kozlov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 23–26, January, 1988.

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Kozintsev, S.I., Basalaeva, L.I., Gladkikh, L.V. et al. Catalytic hydroamination of furfuryl and tetrahydrofurfuryl alcohols with nitriles. Chem Heterocycl Compd 24, 19–22 (1988). https://doi.org/10.1007/BF00475557

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  • DOI: https://doi.org/10.1007/BF00475557

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