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2-Pyridones

VI. Nitration of 6-phenyl-2-pyridone

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The nitration of 6-phenyl-2-pyridone with 70% nitric acid, nitronium tetrafluoroborate, and acetyl nitrate has been studied for the first time. It was shown that, depending on the reaction temperature, the nitro group enters the 3 or 5 position of the heterocyclic ring. 3- Nitro-6-(p-nitrophenyl)-2-pyridone is formed by the action of fuming nitric acid on 6-phenyl-2-pyridone. The structures of the nitropyridones obtained were proved by PMR spectroscopy.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. P. Shusherina & T. I. Likhomanova

Authors
  1. N. P. Shusherina
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  2. T. I. Likhomanova
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Additional information

See Zh. Organ. Khim., 7, 387 (1971) for communication V.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1374–1378, October, 1972.

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Shusherina, N.P., Likhomanova, T.I. 2-Pyridones. Chem Heterocycl Compd 8, 1242–1245 (1972). https://doi.org/10.1007/BF00475539

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  • DOI: https://doi.org/10.1007/BF00475539

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