Chemistry of Heterocyclic Compounds

, Volume 8, Issue 10, pp 1185–1188 | Cite as

Reactions of pyrylium salts with nucleophilic agents

  • S. N. Baranov
  • M. A. Dumbai
  • S. V. Krivun
Article

Abstract

The reaction of γ-unsubstituted pyrylium salts with alkali-metal cyanides gives cyano- and carboxy-substituted pyrans and pyrylium salts, while the reaction with sodium sulfide gives dipyranyl sulfides. A phthalimide derivative of pyran is obtained from 2,6-diphenylpyrylium perchlorate and potassium phthalimide, while pyrylium cations react with zinc to give the corresponding dipyranyls.

Keywords

Sodium Zinc Potassium Sulfide Organic Chemistry 

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • S. N. Baranov
    • 1
  • M. A. Dumbai
    • 1
  • S. V. Krivun
    • 1
  1. 1.Donetsk Physical-Organic Chemistry Branch, Institute of Physical ChemistryAcademy of Sciences of the Ukrainian SSRUSSR

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