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Chemistry of Heterocyclic Compounds

, Volume 23, Issue 1, pp 8–15 | Cite as

Rotational isomers of the radical-anions of 2-carbonyl-containing derivatives of 5-nitrofuran

  • R. A. Gavar
  • L. Kh. Baumane
  • Ya. P. Stradyn'
  • M. B. Fleisher
  • M. Chernaeva
  • Ya. Kovach
Article

Abstract

The radical-anions of 2-carbonyl-containing derivatives of 5-nitrofuran were obtained by electrochemical generation. Their ESR spectra indicate the existence of a mixture of O,O-cis and O,O-trans rotational isomers. The parameters of the isomers were identified by INDO calculations. The more polar form (the cis isomer) is more stable in polar media.

Keywords

Organic Chemistry Polar Medium Polar Form Rotational Isomer Electrochemical Generation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • R. A. Gavar
    • 1
    • 2
  • L. Kh. Baumane
    • 1
    • 2
  • Ya. P. Stradyn'
    • 1
    • 2
  • M. B. Fleisher
    • 1
    • 2
  • M. Chernaeva
    • 1
    • 2
  • Ya. Kovach
    • 1
    • 2
  1. 1.Institute of Organic SynthesisAcademy of Sciences of the Latvian SSRRiga
  2. 2.Slovak Higher Technical SchoolBratislavaCzechoslovakia

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