Chemistry of Heterocyclic Compounds

, Volume 6, Issue 1, pp 85–88 | Cite as

A study of the formation reactions of amides of 2-benzthiazolylsulphenic acid from N-chloramines and 2-mercapto benzthiazone

  • V. A. Ignatov
  • P. A. Pirogov
Article
  • 25 Downloads

Abstract

A study was made of the mechanism of the reaction between N-chloramines and 2-mercapto benzthiazole in water and in inert solvents. It was shown that in water and alcohol, in addition to the formation of sulfenamides, there is an oxidation reaction of 2-mercapto benzthiazole by hypochlorous acid to the disulfide.

Keywords

Oxidation Alcohol Organic Chemistry Amide Disulfide 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    V. A. Ignatov, P. A. Pirogov, and M. S. Fel'dshtein, ZhOrKh, 4, 2025, 1968.Google Scholar
  2. 2.
    K. K. Ingold, Mechanism of Reactions and Structure of Organic Compounds [Russian translation], IL, Moscow, 279, 1959.Google Scholar
  3. 3.
    B. V. Nekrasov, A Course in General Chemistry [in Russian], GKhI, Moscow-Leningrad, 349, 1954.Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • V. A. Ignatov
    • 1
  • P. A. Pirogov
    • 1
  1. 1.Scientific-Research Institute of Chemical Additives for PolymersTambov

Personalised recommendations