Chemistry of Heterocyclic Compounds

, Volume 6, Issue 1, pp 85–88 | Cite as

A study of the formation reactions of amides of 2-benzthiazolylsulphenic acid from N-chloramines and 2-mercapto benzthiazone

  • V. A. Ignatov
  • P. A. Pirogov


A study was made of the mechanism of the reaction between N-chloramines and 2-mercapto benzthiazole in water and in inert solvents. It was shown that in water and alcohol, in addition to the formation of sulfenamides, there is an oxidation reaction of 2-mercapto benzthiazole by hypochlorous acid to the disulfide.


Oxidation Alcohol Organic Chemistry Amide Disulfide 
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  1. 1.
    V. A. Ignatov, P. A. Pirogov, and M. S. Fel'dshtein, ZhOrKh, 4, 2025, 1968.Google Scholar
  2. 2.
    K. K. Ingold, Mechanism of Reactions and Structure of Organic Compounds [Russian translation], IL, Moscow, 279, 1959.Google Scholar
  3. 3.
    B. V. Nekrasov, A Course in General Chemistry [in Russian], GKhI, Moscow-Leningrad, 349, 1954.Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • V. A. Ignatov
    • 1
  • P. A. Pirogov
    • 1
  1. 1.Scientific-Research Institute of Chemical Additives for PolymersTambov

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