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Heteroadamantanes and their derivatives

15. Synthesis of derivatives of 9-amino-3,6-diazahomoadamantanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

9-Amino-3,6-diazahomoadamantanes were prepared from 3,6-diazahomo-adamantan-9-ones through oximes and converted into 9-acetylamino-3,6-diaza-homoadamantanes with acetic anhydride. It was shown that oximes with one substituent in the nodal position are formed as one geometric isomer with the E-position of the hydroxyl group relative to the substituent.

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Literature cited

  1. A. I. Kuznetsov, I. A. Vladimirova, T. M. Serova, and A. S. Moskovkin, Khim. Geterotsikl. Soedin., No. 6, 804 (1991).

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  2. A. I. Kuznetsov and A. I. Vladimirova, Khim. Geterotsikl. Soedin., No. 12, 1700 (1988).

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  3. A. I. Kuznetsov, I. A. Vladimirova, E. B. Basargin, M. Kh. Ba, A. S. Moskovkin, and M. Ya. Botnikov, Khim. Geterotsikl. Soedin., No. 5, 675 (1990).

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Authors and Affiliations

  1. M. V. Lomonosov Institute of Precision Chemical Technology, 119435, Moscow

    A. I. Kuznetsov, I. A. Vladimirova, T. M. Serova & A. S. Moskovkin

Authors
  1. A. I. Kuznetsov
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  2. I. A. Vladimirova
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  3. T. M. Serova
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  4. A. S. Moskovkin
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Additional information

See [1] for Communication 14.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 643–647, May, 1992.

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Kuznetsov, A.I., Vladimirova, I.A., Serova, T.M. et al. Heteroadamantanes and their derivatives. Chem Heterocycl Compd 28, 541–545 (1992). https://doi.org/10.1007/BF00475253

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  • DOI: https://doi.org/10.1007/BF00475253

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