Chemistry of Heterocyclic Compounds

, Volume 8, Issue 7, pp 810–812 | Cite as

Heterofunctional condensation of chlorosilanes with tetra- and hexaphenylsiloxanediols

  • K. A. Andrianov
  • A. B. Zachernyuk
  • S. A. Danielov
Article
  • 36 Downloads

Abstract

A number of new chloro- and hydrochlorosiloxanes with cyclic and linear structures were synthesized by the condensation of tetraphenyldisiloxane-1,3-diol and hexaphenyltrisiloxane-1,5-diol with silicon tetrachloride and trichlorosilane. The effects of the starting ratio of the reactants and dilution on the reaction rates and yields of cyclosiloxanes were studied.

Keywords

Silicon Organic Chemistry Diol Chloro Tetrachloride 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    F. R. Mayo, J. Polymer Sci., 55, 65 (1961).Google Scholar
  2. 2.
    T. C. Wu and C. A. Hirt, J. Organomet. Chem., 11, 17 (1968).Google Scholar
  3. 3.
    K. A. Andrianov, Dokl. Akad. Nauk SSSR, 191, 347 (1970).Google Scholar
  4. 4.
    G. I. Harris, J. Am. Chem. Soc., 92, 488 (1970).Google Scholar
  5. 5.
    C. A. Burkhard, J. Am. Chem. Soc., 67, 2173 (1945).Google Scholar
  6. 6.
    G. I. Harris, J. Chem. Soc., 5978 (1963).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • K. A. Andrianov
    • 1
  • A. B. Zachernyuk
    • 1
  • S. A. Danielov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations