Abstract
Stereoisomers of 6-halomethyl-2-hydroxymethyl-1, 4-dioxanes have been obtained via the cyclization of the monoallyl ether of glycerol. The stereoisomeric bromides differ considerably in their physical properties. The bromine atoms of the stereoisomers differ in their reactivity towards thiourea.
References
A. N. Nesmeyanov and I. F. Lutsenko, Izv. AN SSSR, OKhN, 296, 1943.
R. K. Summerbell and I. R. Stephens, J. Am. Chem. Soc., 76, 731, 1954.
R. K. Summerbell and Sh. R. Forrester, J. Org. Chem., 26, 4834, 1961.
L. H. Werner and C. R. Sholz, US Pat. 2790812, 1957.
A. P. Kilimov, M. A. Svechnikova, V. I. Shevchenko, V. V. Smirnov, F. V. Kvasnyuk-Mudryi, and S. B. Zotov, KhGS [Chemistry of Heterocyclic Compounds], 579, 1967.
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Zotov, S.B., Smirnov, V.V., Kvasnyuk-Mudryi, F.V. et al. Synthesis of 2, 6-derivatives of 1, 4-dioxane. Chem Heterocycl Compd 3, 872–873 (1967). https://doi.org/10.1007/BF00474897
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DOI: https://doi.org/10.1007/BF00474897